Shear-Strained Silicon Quantum Wells for Valley Splitting

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Solution Overview

Problem

Existing silicon quantum dot qubits face challenges with variable and small energy spacing between ground and excited valley states due to degenerate valleys, leading to decoherence, which existing strategies like sharp interfaces and germanium concentration modulations struggle to address consistently.

Innovation Solution

Heterostructures with shear-strained silicon quantum wells seeded with germanium, featuring oscillating germanium concentration profiles and trenches aligned along the [110] crystallographic direction, enhance valley splitting through a combination of shear strain and Ge concentration oscillations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If sharp interfaces are engineered in thin quantum wells to achieve large valley splittings, then valley splitting increases, but device variability increases due to interface imperfections

Engineering Contradiction:
Improvevalley splitting consistencyVSAvoidinterface sharpness
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the approach from relying on interface sharpness to controlling bulk material parameters. Specifically, it uses shear strain (εxy) applied to the silicon quantum well and oscillating germanium concentration profiles to achieve valley splitting. This shifts the control mechanism from interface geometry to bulk material properties, reducing sensitivity to interface imperfections and improving device consistency.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces local variations in germanium concentration within the silicon quantum well through oscillating profiles. These localized Ge-rich regions create specific strain fields and potential landscapes that enhance valley splitting. The local quality modification allows precise control of electronic structure without requiring perfect global interface sharpness.

Inventive Principle:
Principle #3Local quality

2Reliability

If germanium concentration modulations are used to achieve large valley splittings, then valley splitting increases, but manufacturing complexity increases due to precise concentration control requirements

Engineering Contradiction:
Improvevalley splitting magnitudeVSAvoidconcentration profile control
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges two mechanisms—shear strain and germanium concentration oscillations—to achieve enhanced valley splitting. The shear strain provides a baseline enhancement, while the oscillating Ge concentration profiles provide additional tuning capability. This combination allows achieving large valley splitting through a more robust dual-mechanism approach rather than relying solely on precise concentration control.

Inventive Principle:
Principle #5Merging (Combining)

3Ease of manufacture

If long-wavelength germanium modulations are used, then manufacturing is easier, but valley splitting is limited due to lack of shear strain

Engineering Contradiction:
Improvegermanium modulation fabricationVSAvoidvalley splitting magnitude
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent creates a composite structure within the silicon quantum well by incorporating oscillating germanium concentration profiles. This composite material approach combines Si and Ge in a controlled oscillating pattern, leveraging the beneficial properties of both materials. The Ge-rich regions provide local strain and potential modulation, while the Si matrix maintains the overall quantum well structure, achieving both manufacturability and enhanced valley splitting.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heterostructures achieve consistent and large valley splitting, improving qubit state control and spin-orbit coupling without relying on atomically sharp interfaces, enhancing scalability and reliability of quantum computing systems.

Implementation Method 1

This leads to a small energy spacing between ground and excited valley states, called valley splitting, which causes decoherence in qubits if not sufficiently large

Methodology Applied
Scientific EffectValley splitting:

Implementation Method 2

a quantum well comprising a layer of shear-strained germanium-seeded silicon disposed between the first quantum barrier and the second quantum barrier

Methodology Applied
Scientific EffectShear strain: Shear Stress

Implementation Method 3

the layer of germanium-seeded silicon has an oscillating germanium concentration along its thickness direction (z)

Methodology Applied
Scientific EffectGermanium concentration oscillations:

Implementation Method 4

the one or more electrostatic gates are configured to apply a controllable potential to the quantum well that confines electrons in the quantum well in three dimensions

Methodology Applied
Scientific EffectElectrostatic confinement: Electrostatics

Data Source

PatentUS20250254951A1Silicon-germanium heterostructures with shear strain and germanium concentration oscillations for enhanced valley splitting
Publication Date: 2025.08.07 WISCONSIN ALUMNI RES FOUND
  • US20250254951A1 patent drawing
  • US20250254951A1 patent drawing
  • US20250254951A1 patent drawing

AI summary

Heterostructures having germanium-seeded, shear-strained silicon quantum wells are provided. Also provided are gate-controlled qubits based on the heterostructures, and quantum computing systems based on the qubits. The heterostructures include a quantum well of germanium-seeded silicon positioned between two quantum barriers of germanium or a silicon-germanium alloy. The silicon of the quantum well is under a shear strain and is seeded with germanium such that the germanium concentration in the quantum well has an oscillating profile.