SHG Metrology with Pump-Probe Lasers for Defect Quantification

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Solution Overview

Problem

Existing SHG-based metrology tools face limitations in distinguishing between interfacial properties and quantifying contaminants, such as differentiating between gettered contaminants and bond voids, due to their reliance on relative measurements rather than precise quantitative analysis.

Innovation Solution

The use of a pump and probe system with a high average power, low peak power pump laser and a high peak power, low average power probe laser to generate and analyze SHG signals, allowing for faster and more accurate determination of threshold energy for carrier injection and enabling the differentiation and quantification of defects and contaminants by monitoring transient electric field decay.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional SHG-based metrology tools use relative measurements, then the measurement process is simple, but the ability to distinguish between interfacial properties and quantify contaminants is limited

Engineering Contradiction:
Improvequantification precisionVSAvoidsystem complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent segments the measurement process into distinct phases using pump and probe laser beams with different functions. The pump beam prepares the sample state while the probe beam performs the actual measurement, allowing separate optimization of each function and enabling precise quantification without overwhelming system complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces transient electric field decay as an intermediary phenomenon that mediates between the laser excitation and the final measurement signal. This intermediary provides a time-resolved signature that enables precise differentiation and quantification of contaminants while maintaining manageable system complexity through temporal separation

Inventive Principle:
Principle #24Intermediary (Mediator)

2Measurement precision

If a single high power laser is used for SHG measurement, then the system is simpler to operate, but the ability to determine threshold energy and differentiate defect types is reduced

Engineering Contradiction:
Improvedefect differentiation precisionVSAvoidoperation simplicity
Core Design Contradiction:
Measurement precisionVSEase of operation

Solution Approach 1:

The patent divides the laser system into two specialized beams: a pump laser optimized for inducing transient electric field decay and a probe laser optimized for detecting SHG signals. This segmentation allows each beam to be optimized for its specific function, improving defect differentiation precision while the automated sequencing maintains operational simplicity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs periodic pumping and probing cycles with controlled time intervals. The pump beam excites the sample at regular intervals, and the probe beam measures the transient decay at predetermined times. This periodic action enables precise threshold energy determination and defect type differentiation through temporal signal analysis

Inventive Principle:
Principle #19Periodic action

3Measurement precision

If fast transient electric field decay monitoring is implemented, then real-time quantification of contaminants is enabled, but the measurement and processing time increases

Engineering Contradiction:
Improvecontaminant quantification precisionVSAvoidmeasurement time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent performs preliminary action by having the pump laser prepare the sample state in advance before the probe laser performs the actual measurement. This pre-excitation creates a transient electric field decay signature that contains the contamination information, allowing the probe to quickly capture the signal without requiring prolonged measurement times

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses periodic pumping and probing with optimized cycle times. By repeating the measurement cycle at appropriate intervals and capturing the transient decay at specific time points, the system achieves precise contaminant quantification while maintaining efficient throughput through temporal multiplexing

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables real-time or post-processing quantification of defect types and contaminant species, providing precise data for process adjustments and improving semiconductor device fabrication quality.

Implementation Method 1

Second-Harmonic generation is a non-linear optical effect comprising conversion of light having one frequency into light at twice that frequency upon scattering from some types of materials, structures, and geometries

Methodology Applied
Scientific EffectSecond-harmonic generation: Second Harmonic Generation

Implementation Method 2

determination of threshold energy for carrier injection and enabling the differentiation and quantification of defects and contaminants by monitoring transient electric field decay

Methodology Applied
Scientific EffectCarrier injection: Photoconductivity

Data Source

PatentUS20240077302A1Dimensional metrology using non-linear optics
Publication Date: 2024.03.07 FEMTOMETRIX INC
  • US20240077302A1 patent drawing
  • US20240077302A1 patent drawing
  • US20240077302A1 patent drawing

AI summary

Systems and methods are disclosed for using second-harmonic generation of light to monitor the manufacturing process for changes that can affect the performance or yield of produced devices and/or determining critical dimensions of the produced device.