Co-doped SiC Semiconductor Device Resistance Reduction

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The challenge in manufacturing semiconductor devices using silicon carbide (SiC) is the difficulty in lowering resistance in p-type and n-type impurity regions due to low solid solubility limits and deep impurity levels, which hinders the development of high-performance power semiconductor devices.

Innovation Solution

The implementation of co-doping techniques involving specific combinations of p-type and n-type impurities, such as aluminum (Al) and nitrogen (N), or boron (B) and phosphorus (P), within SiC, where the concentration ratio of the n-type impurity to the p-type impurity is between 0.33 and 0.995, forming stable pair or trimer structures that reduce strain and increase solubility limits, thereby improving carrier generation and reducing resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional single doping is used in SiC, then the doping process is simple, but the resistance in impurity regions cannot be lowered due to low solid solubility limits and deep impurity levels

Engineering Contradiction:
Improveresistance reductionVSAvoiddoping process complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent combines p-type and n-type doping into a single co-doping process, introducing both Al and N impurities simultaneously during crystal growth. This merging of doping functions achieves resistance reduction through the synergistic effect of Al (providing holes) and N (forming shallow donor levels when paired with Al), while maintaining manufacturing simplicity by performing both doping operations in one integrated process step rather than separate sequential steps.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent creates a composite doped structure in SiC by introducing two different types of impurities (Al and N) that form specific pair structures (Al-N pairs) within the crystal lattice. This composite approach at the atomic level allows the material to exhibit enhanced electrical properties that neither impurity alone could achieve, specifically lowering resistance through the formation of shallow donor levels by N when paired with Al acceptors.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If high concentration of single type impurity is introduced, then carrier concentration increases, but solid solubility limit is exceeded causing crystal defects

Engineering Contradiction:
Improvecarrier concentrationVSAvoidcrystal structure stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent merges p-type Al doping and n-type N doping into a co-doping scheme where both impurities are introduced together at concentrations that would individually exceed solubility limits. The Al and N atoms form stable pair structures (Al-N pairs) within the SiC lattice, allowing higher total impurity concentrations to be incorporated without creating excessive crystal defects, thereby achieving high carrier concentration while maintaining crystal stability.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent uses N impurity atoms as intermediaries that form pair structures with Al atoms. These Al-N pair structures act as mediators that stabilize the crystal lattice when high concentrations of impurities are present. The N atoms in these pairs create shallow donor levels that contribute to carrier concentration while the paired structure itself stabilizes the composition, preventing excessive crystal defects that would otherwise occur at such high doping levels.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If Al and N are co-doped in SiC, then solubility limit increases and resistance decreases, but the doping process becomes more complex

Engineering Contradiction:
Improveresistance and solubility improvementVSAvoiddoping process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by pre-establishing the co-doping mechanism and Al-N pair formation principles before actual device manufacturing. The solubility enhancement and resistance reduction effects are achieved through this pre-planned co-doping strategy, which simplifies the overall process compared to attempting to achieve the same results through multiple separate doping steps or post-growth treatments.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent merges the functions of increasing solubility and reducing resistance into a single co-doping operation. By introducing Al and N simultaneously during crystal growth, the process achieves both objectives together: the Al-N pair structures increase the effective solubility limit for impurity incorporation while the formation of shallow donor levels by N and hole contribution by Al work synergistically to reduce resistance, all within one integrated doping process step.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in reduced sheet resistance, lower resistivity, and enhanced energization breakdown tolerance, allowing for the creation of high-performance SiC semiconductor devices with improved carrier activation and reduced crystal defects.

Implementation Method 1

the element A and the element D form at least a first combination or a second combination... forming stable pair or trimer structures that reduce strain and increase solubility limits

Methodology Applied
Scientific EffectPair/trimer formation: Chemical Bonding

Implementation Method 2

a p-type impurity and an n-type impurity are implanted... Where the p-type impurity is an element A and the n-type impurity is an element D

Methodology Applied
Scientific EffectIon implantation: Ion Implantation

Data Source

PatentUS9559172B2Semiconductor device and method of manufacturing the same
Publication Date: 2017.01.31 KK TOSHIBA
  • US9559172B2 patent drawing
  • US9559172B2 patent drawing
  • US9559172B2 patent drawing

AI summary

A semiconductor device of an embodiment includes a p-type SiC impurity region containing a p-type impurity and an n-type impurity. Where the p-type impurity is an element A and the n-type impurity is an element D, the element A and the element D form a combination of Al (aluminum), Ga (gallium), or In (indium) and N (nitrogen), and/or a combination of B (boron) and P (phosphorus). The ratio of the concentration of the element D to the concentration of the element A in the above combination is higher than 0.33 but lower than 0.995, and the concentration of the element A forming part of the above combination is not lower than 1×1018 cm−3 and not higher than 1×1022 cm−3.