SiC-Buffered GaN Substrate for High Voltage Reliability

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Solution Overview

Problem

Existing methods for manufacturing compound semiconductor substrates using GaN layers face challenges in achieving high vertical withstand voltage while minimizing current collapse, as doping GaN with carbon increases defects and traps electrons, leading to degraded performance.

Innovation Solution

A method involving the formation of a SiC layer on a Si substrate, followed by alternating AlN layers at specific temperature ranges, and subsequent growth of nitride semiconductor layers to improve crystal quality and reduce defects, thereby enhancing vertical withstand voltage and reducing current collapse.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If GaN layer is doped with carbon to improve vertical withstand voltage, then insulation breakdown resistance increases, but defects increase and electron trapping sites increase leading to current collapse

Engineering Contradiction:
Improvevertical withstand voltageVSAvoidcurrent collapse resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent introduces a SiC layer as an intermediary between the Si substrate and the GaN layer. This SiC buffer layer mediates the lattice mismatch and thermal expansion differences, enabling high-quality GaN growth without carbon doping. The SiC layer has a lattice constant intermediate between Si and GaN, providing a gradual transition that reduces dislocation density and eliminates the need for harmful carbon doping to achieve high withstand voltage.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the substrate material parameter from pure Si to SiC-buffered Si substrate. This parameter change fundamentally alters the growth conditions for GaN, enabling the formation of high-quality crystalline structures without requiring carbon doping. The SiC buffer layer modifies the thermal and structural parameters of the substrate system, allowing GaN to grow with fewer defects and without the need for compensatory doping.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If Si substrate is used for GaN device, then manufacturing cost is reduced, but warpage and cracks occur due to lattice constant and thermal expansion differences

Engineering Contradiction:
Improvesubstrate costVSAvoidsubstrate flatness and layer integrity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The SiC layer serves as a mediator between the Si substrate and the GaN layer. It compensates for the lattice mismatch and thermal expansion coefficient differences between Si and GaN, preventing warpage and cracks while maintaining the cost advantage of using Si substrates. The SiC buffer layer absorbs the mechanical stress caused by the material property differences.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent applies local quality improvement by introducing a SiC buffer layer only at the critical interface region between Si substrate and GaN layer. This localized intervention addresses the specific problem of lattice mismatch and thermal stress at the substrate interface without requiring changes to the entire substrate or device structure, thus maintaining cost effectiveness while improving manufacturing precision.

Inventive Principle:
Principle #3Local quality

3Reliability

If AlN buffer layer is formed at high temperature to improve crystal quality, then defect density decreases, but manufacturing process complexity increases

Engineering Contradiction:
Improvecrystal qualityVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent changes the temperature parameter for AlN buffer layer formation to an optimized range of 700-1000°C. This parameter optimization achieves high crystal quality and low defect density without requiring excessively complex manufacturing processes. The specific temperature range balances crystal growth quality with process feasibility and equipment requirements.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent segments the buffer layer structure into multiple functional layers: SiC buffer layer for lattice matching, followed by AlN buffer layer for defect reduction. This segmentation allows each layer to perform its specific function optimally, achieving high crystal quality through a systematic multi-layer approach rather than relying on a single complex process step.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in a compound semiconductor substrate with improved crystalline quality, reduced electron trapping sites, and increased vertical withstand voltage, effectively addressing the current collapse issue while maintaining high insulation breakdown voltage.

Implementation Method 1

a step to form a SiC layer on a Si substrate

Methodology Applied
Scientific EffectChemical Vapor Deposition: Chemical Vapour Deposition

Implementation Method 2

a step to form a first AlN layer having a thickness of 12 nanometers or more and 100 nanometers or less on the SiC layer at 700 degrees Celsius or more and 1000 degrees Celsius or less

Methodology Applied
Scientific EffectThermal energy: Heating

Implementation Method 3

a step to form a first AlN layer having a thickness of 12 nanometers or more and 100 nanometers or less on the SiC layer at 700 degrees Celsius or more and 1000 degrees Celsius or less

Methodology Applied
Scientific EffectPhysical Vapor Deposition: Physical Vapour Deposition

Implementation Method 4

a step to form a first nitride semiconductor layer containing Al on the second AlN layer, a step to form a GaN layer on the first nitride semiconductor layer

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Data Source

PatentUS11476115B2Compound semiconductor substrate comprising a SiC layer
Publication Date: 2022.10.18 AIR WATER INC
  • US11476115B2 patent drawing
  • US11476115B2 patent drawing
  • US11476115B2 patent drawing

AI summary

A method for manufacturing a compound semiconductor substrate comprises: a step to form an SiC (silicon carbide) layer on a Si (silicon) substrate, a step to form a LT (Low Temperature)-AlN (aluminum nitride) layer with a thickness of 12 nanometers or more and 100 nanometers or less on the SiC layer at 700 degrees Celsius or more and 1000 degrees Celsius or less, a step to form a HT (High Temperature)-AlN layer on the LT-AlN layer at a temperature higher than the temperature at which the LT-AlN layer was formed, a step to form an Al (aluminum) nitride semiconductor layer on the HT-AlN layer, a step to form a GaN (gallium nitride) layer on the Al nitride semiconductor layer, and a step to form an Al nitride semiconductor layer on the GaN layer.