SiC Ceramic Component via Binder Jetting and Carbonization

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Solution Overview

Problem

Ceramic components made from silicon carbide with complex geometric structures are difficult to produce due to high hardness, leading to slow production methods like laser sintering, which result in high costs, inhomogeneous temperature fields, warping, and the presence of large pores and free silicon, reducing chemical stability and temperature resistance.

Innovation Solution

A method involving 3D-printing of a silicon carbide green body, followed by impregnation with a sugar, starch, or cellulose solution, or a resin system, carbonization to create a fine-pored carbon skeleton, and subsequent siliconization to fill pores with liquid silicon, reducing free silicon and enhancing microstructure homogeneity and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Shape

If laser sintering method is used to produce complex geometric structures, then production speed is slow, but manufacturing precision and structural complexity are improved

Engineering Contradiction:
Improvegeometric structure complexityVSAvoidproduction speed
Core Design Contradiction:
ShapeVSProductivity

Solution Approach 1:

The patent replaces the laser sintering method (thermal field-based) with a binder jetting method (mechanical deposition-based). In binder jetting, a binder solution is selectively deposited onto powder layers using a printing mechanism, forming green bodies that are then sintered. This substitution eliminates the need for high-energy laser beams, enabling faster production speeds while maintaining the ability to create complex geometric structures through digital slicing and layer-by-layer deposition.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Shape

If laser sintering method is used, then complex geometric structures can be produced, but inhomogeneous temperature field causes warping

Engineering Contradiction:
Improvegeometric structure complexityVSAvoidcomponent warping
Core Design Contradiction:
ShapeVSManufacturing precision

Solution Approach 1:

The patent segments the heating process into two distinct stages: first, a low-temperature drying stage to remove binder solution and form a stable green body with uniform structure; second, a high-temperature sintering stage to densify the ceramic. This segmentation prevents thermal shock and warping by avoiding rapid temperature changes during the forming process, while still enabling complex geometric structures to be produced through the binder jetting method.

Inventive Principle:
Principle #1Segmentation

3Ease of manufacture

If laser sintering method is used, then ceramic components can be produced, but high heat input causes high shrinkage requiring support structures

Engineering Contradiction:
Improvecomponent productionVSAvoidsupport structure requirements
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The patent performs preliminary binder deposition and drying to form a stable green body structure before applying high-temperature sintering. The binder solution acts as a temporary framework that holds the powder particles together during the forming process, preventing collapse and eliminating the need for support structures during sintering. This preliminary action enables complex geometric structures to be produced without requiring additional support systems.

Inventive Principle:
Principle #10Preliminary action

4Ease of manufacture

If binder-solid mixtures in powder form are used, then green bodies can be produced, but segregation occurs reducing homogeneity

Engineering Contradiction:
Improvegreen body productionVSAvoidmixing homogeneity
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The patent uses a liquid binder solution instead of powder binders, applying it through a printing mechanism that deposits the liquid uniformly across the powder layer. The liquid binder penetrates and binds the powder particles together, eliminating segregation issues that occur with powder binders. This hydraulic approach ensures homogeneous distribution of binder and powder, producing uniform green bodies with consistent composition throughout.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces a ceramic component with improved chemical stability, temperature resistance, and mechanical properties, allowing for quick, economical, and complex geometric production with reduced free silicon content and increased silicon carbide content, resulting in higher hardness and strength.

Implementation Method 1

impregnating the green body with a solution selected from the group consisting of a sugar solution, a starch solution or a cellulose solution, or a resin system

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

carbonising the dried or cured green body, wherein a fine-pored, foam-like carbon skeleton is produced

Methodology Applied
Scientific EffectCarbonization: Pyrolysis

Implementation Method 3

siliconising the carbonised green body by infiltrating with liquid silicon

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 4

The silicon carbide particles are spheroidized before being used in the 3D-printing process

Methodology Applied
Scientific EffectSpheroidization:

Data Source

PatentUS11878944B2Ceramic component
Publication Date: 2024.01.23 BREMBO SGL CARBON CERAMIC BRAKES GMBH
  • US11878944B2 patent drawing
  • US11878944B2 patent drawing

AI summary

A ceramic component containing silicon carbide and to the use of the component. The method for producing the ceramic component includes the following steps: a) providing a green body based on SiC, which has been produced by means of a 3D-printing method, b) impregnating the green body with a solution selected from the group consisting of a sugar solution, a starch solution or a cellulose solution, or a resin system comprising a mixture containing at least one resin, at least one solvent and at least one curing agent, the at least one resin and the at least one solvent being different, c) drying or curing the impregnated green body, d) carbonising the dried or cured green body, wherein a fine-pored, foam-like carbon skeleton is produced from the dried solution or a fine-pored, sponge-like carbon skeleton is produced from the cured resin system.