SiC Semiconductor Electrode with Ti-Al-Si Composite Layer

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Solution Overview

Problem

In silicon carbide semiconductor devices, achieving low contact resistance with both n-type and p-type regions while minimizing area dependency is challenging, especially with conventional electrode materials like nickel and aluminum, which are not effective in ohmic contact with both types, and existing methods struggle to provide accurate and timely feedback in manufacturing processes.

Innovation Solution

A method involving a material layer composed of titanium, aluminum, and silicon, with a specific atomic ratio within a triangular pyramidal region, is formed and heated to create an electrode layer that is in ohmic contact with both n-type and p-type regions, ensuring low area dependency and uniform thickness, thereby reducing contact resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional electrode materials like nickel or aluminum are used, then ohmic contact with one type of region (n-type or p-type) is achieved, but effective contact with both n-type and p-type regions simultaneously cannot be achieved

Engineering Contradiction:
Improvecontact resistanceVSAvoidcompatibility with both n-type and p-type regions
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent applies composite materials by creating a multi-layer electrode structure consisting of a first electrode layer (nickel) and a second electrode layer (aluminum) with an intermediate layer in between. This composite structure allows the first electrode layer to provide excellent ohmic contact with n-type regions while the second electrode layer provides good contact with p-type regions, thereby achieving compatibility with both region types simultaneously and reducing overall contact resistance.

Inventive Principle:
Principle #40Composite materials

2Reliability

If electrode area is increased to reduce contact resistance, then contact resistance decreases, but area dependency increases making performance prediction difficult

Engineering Contradiction:
Improvecontact resistanceVSAvoidperformance prediction accuracy
Core Design Contradiction:
ReliabilityVSMeasurement precision

Solution Approach 1:

The patent applies parameter changes by optimizing the thickness parameters of each electrode layer (first electrode layer: 10-100 nm, second electrode layer: 10-100 nm, intermediate layer: 1-10 nm) and controlling the atomic ratios of elements within specific ranges. These parameter optimizations enable achievement of low contact resistance with minimal area dependency, allowing accurate performance prediction even with small electrode areas used in test element group patterns.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If material layer thickness is decreased to improve resolution, then manufacturing precision improves, but contact resistance increases

Engineering Contradiction:
Improveelectrode layer thickness uniformityVSAvoidcontact resistance
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent resolves this contradiction by using a composite multi-layer structure where each layer has optimized thickness. The intermediate layer with specific thickness (1-10 nm) and composition acts as a bridge, ensuring that even when individual layers are thin for manufacturing precision, the overall contact resistance remains low through the synergistic effect of the composite structure.

Inventive Principle:
Principle #40Composite materials

4Ease of manufacture

If conventional single-material electrodes are used, then manufacturing process is simple, but achieving low area dependency and uniform performance across different electrode widths is difficult

Engineering Contradiction:
Improveelectrode formation processVSAvoidperformance uniformity across different electrode widths
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The patent applies composite materials with each layer having controlled composition and thickness. The intermediate layer with specific elemental composition (containing silicon, aluminum, and nickel atoms in controlled ratios) ensures uniform performance characteristics across different electrode widths by creating a stable, reproducible interface structure that maintains consistent electrical properties regardless of electrode area variations.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in a silicon carbide semiconductor device with an electrode layer that maintains low contact resistance across varying electrode widths, from 1 μm to 100 μm, and ensures high uniformity and reliability by controlling the composition and thickness of the electrode layer, improving the prediction of actual device performance.

Implementation Method 1

forming an electrode layer in contact with the n-type region and the p-type region by heating the material layer

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

forming an electrode layer in contact with the n-type region and the p-type region by heating the material layer

Methodology Applied
Scientific EffectIntermetallic compound formation:

Data Source

PatentUS10381453B2Method for manufacturing silicon carbide semiconductor device and silicon carbide semiconductor device
Publication Date: 2019.08.13 MITSUMI ELECTRIC CO LTD
  • US10381453B2 patent drawing
  • US10381453B2 patent drawing
  • US10381453B2 patent drawing

AI summary

A method for manufacturing a silicon carbide semiconductor device includes preparing a silicon carbide layer including an n-type region having an n conductivity type and a p-type region having a p conductivity type, forming a material layer containing titanium, aluminum, and silicon on the n-type region and the p-type region, and forming an electrode layer in contact with the n-type region and the p-type region by heating the material layer. In forming a material layer, composition of the material layer is determined such that a point (x, y, z) (x, y, and z each being a numeric value greater than 0) representing a composition ratio among titanium, aluminum, and silicon is included in a first triangular pyramidal region having four points of the origin (0, 0, 0), a point (1, 2, 2), a point (2, 1, 2) and a point (2, 2, 1) as vertices.