SiC Epitaxial Wafer Defect Mitigation via Two-Step Growth

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Solution Overview

Problem

Silicon carbide epitaxial wafers often suffer from carrot and triangular defects due to lack of crystallographic uniformity, leading to high voltage leakage and reduced non-defective product rates in semiconductor devices, primarily caused by threading screw dislocations and changes in the C/Si ratio during epitaxial growth.

Innovation Solution

The method involves forming a silicon carbide epitaxial wafer with a substrate having an off-angle orientation and using a two-step epitaxial growth process with etching in between to maintain a consistent C/Si ratio, reducing distortion and defects by forming steps within the epitaxial layer, thereby alleviating carrot and triangular defects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a silicon carbide epitaxial layer is grown continuously without interruption, then productivity is improved, but carrot and triangular defects increase due to distortion accumulation

Engineering Contradiction:
Improveepitaxial growth efficiencyVSAvoidcrystallographic uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The continuous epitaxial growth process is divided into multiple stages: a first growth stage forming an initial layer, followed by an etching stage that removes part of this layer, and then a second growth stage. This segmentation allows distortion to be reset during etching while maintaining overall productivity through continuous processing.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent implements periodic etching during the epitaxial growth process, where growth is interrupted at regular intervals to perform selective etching of distorted regions. This periodic action prevents defect accumulation while maintaining high overall growth efficiency through automated cycle management.

Inventive Principle:
Principle #19Periodic action

2Ease of manufacture

If threading screw dislocations are present in the substrate, then ease of manufacture is improved, but carrot and triangular defects are generated during epitaxial growth

Engineering Contradiction:
Improvesubstrate availabilityVSAvoiddefect-free product rate
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent converts the harmful effect of threading screw dislocations into a beneficial process feature. By performing selective etching at specific growth stages, the dislocation sites that would normally generate defects are instead used as markers for targeted distortion removal, transforming the manufacturing challenge into a controlled defect mitigation strategy.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The etching process acts as an intermediary mechanism between the substrate with dislocations and the final defect-free epitaxial layer. The selective etching removes distorted regions while preserving the underlying dislocation structure, allowing the dislocations to remain in the substrate without propagating defects into the device region.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If the C/Si ratio is changed during epitaxial growth to reduce defects, then manufacturing precision is improved, but process complexity increases

Engineering Contradiction:
Improvedefect reductionVSAvoidepitaxial growth process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent utilizes parameter changes in the C/Si ratio during different growth stages to control defect formation. By adjusting the carbon-to-silicon ratio specifically during the etching and regrowth phases, the process targets distortion removal while maintaining overall process manageability through defined parameter ranges.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces the occurrence of carrot and triangular defects without altering the C/Si ratio, enhancing the uniformity and quality of the epitaxial layer, leading to improved electrical characteristics and increased yield in silicon carbide semiconductor devices.

Implementation Method 1

a film whose impurity concentration is controlled with high accuracy is epitaxially grown on a silicon carbide substrate by a chemical vapor deposition method (CVD method)

Methodology Applied
Scientific EffectEpitaxial growth: Epitaxy

Implementation Method 2

epitaxially grown on a silicon carbide substrate by a chemical vapor deposition method (CVD method)

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Data Source

PatentUS20200321437A1Silicon carbide epitaxial wafer, method for manufacturing silicon carbide epitaxial wafer, and power converter
Publication Date: 2020.10.08 MITSUBISHI ELECTRIC CORP
  • US20200321437A1 patent drawing
  • US20200321437A1 patent drawing
  • US20200321437A1 patent drawing

AI summary

A silicon carbide epitaxial wafer includes a silicon carbide substrate and silicon carbide epitaxial layers formed on the silicon carbide substrate. Each of the silicon carbide epitaxial layers has a triangular defect. The silicon carbide epitaxial layer each have a step inside the triangular defect in the surface morphology of the triangular defect.