SiC Epitaxial Wafer Defect Conversion via High-Rate Growth

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current methods for producing SiC epitaxial wafers with larger sizes, such as 6 inches or more, face challenges in achieving low basal plane dislocation and intrinsic 3C triangular defect densities, which are critical for reducing device killer defects and improving device yield and quality.

Innovation Solution

A method involving a ramping step to gradually adjust crystal growth conditions to high-rate epitaxial growth conditions, including a high-rate growth step with a growth rate of 50 μm/h or more, and a buffer layer with a higher carrier concentration than the drift layer, to convert basal plane dislocations into threading edge dislocations efficiently, thereby reducing defect densities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the size of SiC epitaxial wafer is increased to 6 inches or more, then productivity and device yield are improved, but basal plane dislocation density and intrinsic 3C triangular defect density increase

Engineering Contradiction:
Improvedevice yieldVSAvoiddefect density
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The epitaxial growth process is divided into multiple stages: initial growth stage, intermediate growth stage, and final growth stage. Each stage has optimized growth rates and conditions to progressively manage defect formation while maintaining high productivity for large 6-inch wafers

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Growth rate parameters are dynamically adjusted throughout the epitaxial process. The growth rate is increased from initial low rates to final high rates (50-200 μm/h), allowing control over defect formation while achieving high productivity for large wafers

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If thermal stress is applied to reduce basal plane dislocation density, then manufacturing precision is improved, but process complexity and energy consumption increase

Engineering Contradiction:
Improvebasal plane dislocation densityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

Temperature parameters are optimized within a specific range (1600-2000°C) to naturally promote conversion of basal plane dislocations to threading edge dislocations without requiring additional thermal stress processing steps

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The process leverages the natural tendency of basal plane dislocations to convert to threading edge dislocations under controlled epitaxial conditions, transforming a potentially harmful defect into a less harmful one through optimized growth parameters rather than additional processing

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Manufacturing precision

If C/Si ratio is increased to reduce basal plane dislocation density, then manufacturing precision is improved, but material cost and process complexity increase

Engineering Contradiction:
Improvebasal plane dislocation densityVSAvoidmaterial cost
Core Design Contradiction:
Manufacturing precisionVSQuantity of substance

Solution Approach 1:

The C/Si ratio is optimized within a specific range (0.5-2.0) to achieve effective conversion of basal plane dislocations while avoiding excessive carbon incorporation that would increase material costs and cause other defects

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in SiC epitaxial wafers with basal plane dislocation and intrinsic 3C triangular defect densities of 0.1 pieces/cm2 or less, enhancing device operation, yield, and quality, particularly for larger wafer sizes.

Implementation Method 1

Most of the basal plane dislocations in the SiC single crystal substrate may be converted into threading edge dislocations (TED) during formation of the epitaxial layer

Methodology Applied
Scientific EffectDislocation conversion:

Implementation Method 2

The SiC epitaxial wafer can be obtained by forming (growing) an epitaxial layer (film), which becomes an active region of the device, on a SiC single crystal substrate by using a chemical vapor deposition (CVD) method

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Data Source

PatentUS20190376206A1SiC EPITAXIAL WAFER AND METHOD FOR PRODUCING SAME
Publication Date: 2019.12.12 DENSO CORP
  • US20190376206A1 patent drawing
  • US20190376206A1 patent drawing
  • US20190376206A1 patent drawing

AI summary

This SiC epitaxial wafer includes: a SiC single crystal substrate of which a main surface has an off-angle of 0.4° to 5° with respect to (0001) plane; and an epitaxial layer provided on the SiC single crystal substrate, wherein the epitaxial layer has a basal plane dislocation density of 0.1 pieces/cm2 or less that is a density of basal plane dislocations extending from the SiC single crystal substrate to an outer surface and an intrinsic 3C triangular defect density of 0.1 pieces/cm2 or less.