SiC Epitaxial Wafer CVD Control for Uniform High N-Type Doping

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Solution Overview

Problem

SiC epitaxial wafers with high in-plane uniformity of n-type doping concentration in high concentration layers are challenging to produce, leading to poor carrier recombination effects and defects due to non-uniform doping concentrations.

Innovation Solution

A SiC epitaxial wafer with a high concentration layer having an average doping concentration of 1×10^18/cm^3 to 1×10^19/cm^3 and in-plane uniformity of 30% or less is manufactured using a chemical vapor deposition method, with adjustable C-based and Si-based gas supply pipes to achieve a C/Si ratio of 1.1 to 1.7, ensuring uniform doping distribution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a high concentration layer with high n-type doping concentration is formed to improve carrier recombination effect, then the carrier recombination effect is enhanced, but the in-plane uniformity of doping concentration deteriorates

Engineering Contradiction:
Improvecarrier recombination effectVSAvoidin-plane uniformity of doping concentration
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by optimizing the C/Si ratio in the chemical vapor deposition process to a specific range (1.05 ≤ C/Si ratio < 1.20) and controlling the doping concentration within a defined range (1×10^18/cm³ to 1×10^19/cm³). These parameter adjustments enable simultaneous achievement of high carrier recombination effect and improved in-plane uniformity of doping concentration, resolving the technical contradiction between enhancing carrier recombination and maintaining doping uniformity.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If the doping concentration is increased to improve carrier recombination, then the carrier recombination effect is enhanced, but defects due to non-uniform doping concentration occur

Engineering Contradiction:
Improvecarrier recombination effectVSAvoiddefects due to non-uniform doping
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent resolves this contradiction by precisely controlling the C/Si ratio parameter within the range of 1.05 ≤ C/Si ratio < 1.20 during chemical vapor deposition. This parameter optimization ensures that high doping concentrations (1×10^18/cm³ to 1×10^19/cm³) are achieved uniformly across the wafer surface, thereby enhancing carrier recombination effect while preventing defects caused by non-uniform doping distribution.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If chemical vapor deposition is used to form the epitaxial layer, then the epitaxial growth is achieved, but the in-plane uniformity of high concentration layer doping deteriorates

Engineering Contradiction:
Improveepitaxial growthVSAvoidin-plane uniformity of high concentration layer doping
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent addresses this contradiction by optimizing the C/Si ratio parameter specifically for high concentration layer formation in chemical vapor deposition. By maintaining the C/Si ratio within 1.05 ≤ C/Si ratio < 1.20 and controlling the doping concentration at 1×10^18/cm³ to 1×10^19/cm³, the process achieves both ease of epitaxial growth and high in-plane uniformity of doping concentration in the high concentration layer.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves high in-plane uniformity of the n-type doping concentration, preventing carrier recombination defects and enhancing the quality of the SiC epitaxial wafer by maintaining a uniform doping concentration across the wafer surface.

Implementation Method 1

The epitaxial layer is formed by a chemical vapor deposition (CVD) method or the like

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 2

forming a film by epitaxial growth on a SiC single crystal substrate in the chemical vapor deposition device

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS12166087B2SiC epitaxial wafer and method for manufacturing SIC epitaxial wafer
Publication Date: 2024.12.10 RESONAC CORP
  • US12166087B2 patent drawing
  • US12166087B2 patent drawing
  • US12166087B2 patent drawing

AI summary

A SiC epitaxial wafer of the present invention includes a SiC single crystal substrate, and a high concentration layer that is provided on the SiC single crystal substrate and has an average value of an n-type doping concentration of 1×1018/cm3 or more and 1×1019/cm3 or less, and in-plane uniformity of the doping concentration of 30% or less.