Silicon Carbide Ceramic Sliding Parts with Dual-Size Graphite Lubricants

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Solution Overview

Problem

Conventional sintered silicon carbides exhibit poor sliding properties and are prone to seizing and cracking in a non-lubricated state due to high frictional coefficients and inadequate density, which limits their effectiveness in mechanical seals and other sliding applications.

Innovation Solution

A ceramic sintered body comprising silicon carbide with a combination of fine and coarse graphite solid lubricants, where the fine solid lubricant has a mean particle size of no greater than 5 µm and the coarse solid lubricant has a mean particle size of 10-70 µm, balanced at specific weight ratios to reduce friction and promote dense, crack-resistant structures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If pure sintered silicon carbide is used, then hardness and chemical resistance are improved, but sliding properties deteriorate in non-lubricated state due to high frictional coefficient

Engineering Contradiction:
ImprovehardnessVSAvoidsliding properties
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies composite materials by combining silicon carbide with graphite solid lubricant in specific proportions (graphite: 0.1-5.0 wt%, silicon carbide: 95.0-99.9 wt%). This composite structure maintains the hardness and chemical resistance of silicon carbide while incorporating graphite's low friction properties to improve sliding behavior in non-lubricated conditions.

Inventive Principle:
Principle #40Composite materials

2Reliability

If carbon materials are added to reduce friction, then sliding properties are improved, but density decreases leading to insufficient sealing properties and cracking

Engineering Contradiction:
Improvesliding propertiesVSAvoiddensity
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies parameter changes by precisely controlling the graphite content within 0.1-5.0 wt% and silicon carbide content within 95.0-99.9 wt%, along with controlling particle size distribution (graphite: 1-10 μm, silicon carbide: 3-20 μm). This optimized parameter range reduces friction while maintaining sufficient density (≥2.25 g/cm³) to prevent cracking and ensure sealing properties.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If graphite content is increased to reduce friction further, then sliding properties are improved, but sintering becomes difficult and density decreases

Engineering Contradiction:
Improvesliding propertiesVSAvoidsintering difficulty
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies parameter changes by limiting graphite content to a maximum of 5.0 wt% and controlling particle sizes (graphite: 1-10 μm, silicon carbide: 3-20 μm). This optimized parameter range ensures that graphite provides sufficient friction reduction while maintaining sinterability and achieving adequate density, avoiding the manufacturing difficulties associated with excessive graphite content.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ceramic sintered body achieves excellent sliding properties and minimal cracking even in a non-lubricated state, with a dense structure and improved sealing capabilities, suitable for use in mechanical seals and other sliding parts.

Implementation Method 1

a ceramic sintered body comprising silicon carbide with a combination of fine and coarse graphite solid lubricants

Methodology Applied
Scientific EffectSolid lubrication: Lubrication

Implementation Method 2

balanced at specific weight ratios to reduce friction and promote dense, crack-resistant structures

Methodology Applied
Scientific EffectFriction reduction: Friction

Implementation Method 3

sintered silicon carbides are extremely hard and exhibit good lubricity when used with water lubrication, while their wear resistance and chemical resistance are also excellent

Methodology Applied
Scientific EffectHardness:

Implementation Method 4

a process for production of the ceramic sintered body

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentEP1988067B1Sintered ceramic, slide part therefrom, and process for producing sintered ceramic
Publication Date: 2017.08.30 RESONAC CORP
  • EP1988067B1 patent drawingFigure 1
  • EP1988067B1 patent drawingFigure 2
  • EP1988067B1 patent drawingFigure 3

AI summary

It is an object of the invention to provide a ceramic sintered body that has a dense structure and minimal cracking and that exhibits excellent sliding properties even in a non-lubricated state, as well as a process for its production and sliding parts that employ the same. According to a preferred mode, the sintered body of the invention comprises silicon carbide as the parent material and further contains a solid lubricant A with a mean particle size of no greater than 5 µm and a solid lubricant B with a mean particle size of 10-70 µm.