Silicon Carbide Single Crystal L Dislocation Control

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Solution Overview

Problem

High-quality silicon carbide (SiC) single crystal wafers with low dislocation density are not effectively produced, leading to unsuppressed leakage current issues in device production, as existing methods fail to differentiate between spiral dislocations based on distortion magnitude.

Innovation Solution

The method involves producing SiC single crystals with a spiral dislocation density of L dislocations ≤300/cm², where the burgers vector b satisfies b>+1/3, and growing SiC crystals on substrates with specific off-angles to the {0001} plane, distinguishing between L and nL dislocations to control leakage current.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If the density of spiral dislocation is set to the specified value or lower (2500 cm−2), then the manufacturing precision is improved, but the leakage current is not suppressed

Engineering Contradiction:
Improvedislocation densityVSAvoidleakage current
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent segments the classification of spiral dislocations by introducing the concept of L dislocations with specific burgers vector magnitudes (b>+1/3). This segmentation allows differentiation between dislocation types that have different impacts on leakage current, enabling selective control of dislocation density to suppress leakage current while maintaining acceptable manufacturing precision.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the parameter criteria for acceptable dislocation density from a general threshold (2500 cm−2) to a more specific parameter based on burgers vector magnitude (b>+1/3) and a lower density threshold (≤300 cm−2). This parameter change enables more precise control over the relationship between dislocation density and leakage current suppression.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If existing methods are used to produce SiC single crystal, then the production process is simple, but the leakage current cannot be suppressed

Engineering Contradiction:
Improveproduction processVSAvoidleakage current
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent modifies the production process by implementing specific parameter controls: (1) selecting substrates with off-angles within 10 degrees in the <1120> direction with respect to the {0001} plane, and (2) controlling L dislocation density to ≤300 cm−2. These parameter changes enable leakage current suppression while maintaining relative simplicity in the production process.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies preliminary action by pre-selecting substrates with specific off-angle orientations before crystal growth. This preliminary selection of substrate orientation prepares the system in advance to suppress leakage current during the subsequent crystal growth process, eliminating the need for complex post-processing adjustments.

Inventive Principle:
Principle #10Preliminary action

3Object-generated harmful factors

If the density of L dislocation is reduced to ≤300 cm−2, then the leakage current is suppressed, but the manufacturing complexity increases

Engineering Contradiction:
Improveleakage currentVSAvoidproduction process complexity
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The patent simplifies the control approach by establishing a clear parameter threshold (L dislocation density ≤300 cm−2) and a specific substrate orientation criterion (off-angle within 10 degrees in <1120> direction). These well-defined parameter changes provide straightforward control criteria that reduce manufacturing complexity despite the stricter requirements.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in high-quality SiC single crystals suitable for device production by suppressing leakage current, with the density of L dislocations ≤300/cm², ensuring effective device performance.

Implementation Method 1

growing the silicon carbide single crystal on the surface of the substrate as a seed crystal

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentUS10253431B2Silicon carbide single crystal and method for producing silicon carbide single crystal
Publication Date: 2019.04.09 DENSO CORP
  • US10253431B2 patent drawing
  • US10253431B2 patent drawing
  • US10253431B2 patent drawing

AI summary

A silicon carbide single crystal includes a spiral dislocation. The spiral dislocation includes a L dislocation having a burgers vector defined as b, which satisfies an equation of b&gt;&lt;0001&gt;+1/3&lt;11-20&gt;. The L dislocation has a density equal to or lower than 300 dislocations/cm2, preferably, 100 dislocations/cm2, since the L dislocation has large distortion and causes generation of leakage current. Thus, the silicon carbide single crystal with high quality is suitable for a device production which can suppress the leakage current.