Multi-Layer Silicon Carbide Membrane for Liquid Tin Filtration Stability

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Solution Overview

Problem

Existing filter systems for liquid metals like liquid tin face challenges such as high temperature handling, reactivity with materials, particulate formation, and stress from freeze-thaw cycles, leading to equipment clogging and membrane degradation.

Innovation Solution

A multi-layer silicon carbide filter membrane is developed, comprising a fine and coarse porous silicon carbide layer, with the coarse layer downstream, to reduce particulate formation and prevent silicon carbide particles from entering the liquid flow.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a single-layer fine porous silicon carbide membrane is used for filtration, then filtration precision is improved, but the membrane becomes susceptible to particulate formation and structural degradation

Engineering Contradiction:
Improvefiltration precisionVSAvoidmembrane stability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The filter membrane is divided into multiple layers with different pore sizes. The fine porous silicon carbide layer provides high filtration precision by capturing small particulates, while the coarse porous silicon carbide layer provides structural support and reduces overall membrane stress. This segmentation allows each layer to specialize in one function, resolving the contradiction between fine filtration and membrane stability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite structure combining fine porous silicon carbide and coarse porous silicon carbide in a multi-layer configuration. This composite approach leverages the advantages of both materials: the fine porous layer for high precision filtration and the coarse porous layer for mechanical strength and stress distribution, thereby achieving both high filtration precision and membrane reliability.

Inventive Principle:
Principle #40Composite materials

2Temperature

If the filter membrane operates at high temperature, then liquid metal processing capability is improved, but thermal stress causes membrane degradation and breakage

Engineering Contradiction:
Improveoperating temperatureVSAvoidmembrane strength
Core Design Contradiction:
TemperatureVSStrength

Solution Approach 1:

The membrane is segmented into multiple layers that can distribute thermal stress more effectively. The coarse porous silicon carbide layer, with its larger pore structure and higher mechanical strength, acts as a stress-bearing layer that protects the fine porous layer from thermal degradation while maintaining high-temperature operation capability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the membrane have different properties optimized for their specific functions. The coarse porous layer has higher mechanical strength and thermal shock resistance for structural integrity, while the fine porous layer has optimized pore structure for filtration. This local quality differentiation allows the membrane to withstand high temperatures without degradation.

Inventive Principle:
Principle #3Local quality

3Adaptability or versatility

If the liquid metal undergoes freeze-thaw cycles, then processing flexibility is improved, but repeated stress causes filter membrane fragmentation

Engineering Contradiction:
Improveprocessing flexibilityVSAvoidmembrane service life
Core Design Contradiction:
Adaptability or versatilityVSDuration of action of stationary object

Solution Approach 1:

The coarse porous silicon carbide layer serves as a cushioning layer that absorbs and distributes the mechanical stress from freeze-thaw cycles before it reaches the fine porous layer. This pre-protection mechanism prevents stress concentration and micro-crack formation, thereby extending the membrane's service life while maintaining processing flexibility.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Solution Approach 2:

The composite multi-layer structure combines materials with different mechanical properties to create a membrane that is resilient to cyclic stress. The coarse porous silicon carbide provides toughness and stress distribution, while the fine porous silicon carbide maintains filtration performance, together enabling the membrane to withstand repeated freeze-thaw cycles.

Inventive Principle:
Principle #40Composite materials

4Quantity of substance

If liquid tin is filtered through downstream equipment, then particulate removal is improved, but equipment clogging occurs due to particulate formation

Engineering Contradiction:
Improveparticulate removal efficiencyVSAvoidequipment clogging
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The multi-layer membrane structure segments the filtration process into different stages. The fine porous layer captures small particulates that would otherwise pass through and cause downstream clogging, while the coarse porous layer handles larger particulates and provides structural stability. This segmentation ensures comprehensive particulate removal without compromising membrane integrity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention converts the potential harm of fine porous membrane fragility into a benefit by using it in combination with a coarse porous support layer. The fine porous layer's high filtration capability is preserved while the coarse porous layer protects it from stress-induced particulate formation, thereby eliminating downstream clogging without sacrificing filtration efficiency.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multi-layer membrane significantly reduces silicon carbide particulates at downstream surfaces, enhancing filtration efficiency and preventing equipment clogging, even under high temperature and pressure conditions.

Implementation Method 1

passing the liquid metal through the filter membrane

Methodology Applied
Scientific EffectPhysical filtration: Filter (physical)

Data Source

PatentEP3648876B1Silicon carbide filter membrane and methods of use
Publication Date: 2026.04.22 ENTEGRIS INC
  • EP3648876B1 patent drawingFigure 1A~1B
  • EP3648876B1 patent drawingFigure 2A~2B

AI summary

Described are silicon carbide filters for use with liquid metals such as liquid tin, as well as methods of using such a filter to remove particles from the liquid metal, and systems and processes that use the filtered liquid metal.