SiC Membrane Sintering for One-Step Pore and Surface Control

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Solution Overview

Problem

Existing methods for regulating the pore structure and surface properties of silicon carbide (SiC) membranes are complex, costly, and often require additional post-treatment, which affects mechanical strength and increases production time, limiting their efficiency in oil-water separation and emulsion preparation.

Innovation Solution

A method that regulates the pore structure and surface properties of SiC membranes by controlling molding pressure and sintering temperature without adding a pore former, using NaA molecular sieve waste powder, industrial grade sodium silicate, and zirconia as sintering aids, and adjusting milling speed and temperature profiles to form neck connections among SiC particles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If post-treatment modification methods are used to improve surface properties, then hydrophilic and hydrophobic properties are improved, but preparation processes and preparation period increase

Engineering Contradiction:
Improvesurface propertiesVSAvoidpreparation processes
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by incorporating surface modification agents into the green body before sintering. The green body is prepared with agents such as silane coupling agents or surface treatment powders mixed into the ceramic powder, so that surface modification occurs during the sintering process itself rather than requiring separate post-treatment steps. This integrates the surface modification function into the main fabrication process, eliminating additional processing steps while achieving the desired surface properties.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent merges the surface modification function with the sintering process. By combining the addition of surface modification agents into the green body preparation step with the subsequent sintering operation, the patent achieves both pore structure formation and surface property modification in a single integrated process flow, rather than requiring separate post-treatment operations.

Inventive Principle:
Principle #5Merging (Combining)

2Manufacturing precision

If pore formers are added to regulate pore structure, then porosity and pore size are controlled, but mechanical strength decreases

Engineering Contradiction:
Improvepore structureVSAvoidmechanical strength
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The patent applies parameter changes by controlling sintering temperature and holding time to regulate pore structure without adding pore formers. By adjusting sintering parameters (temperature profile, duration), the patent achieves precise control over pore size distribution and porosity while maintaining the structural integrity and mechanical strength of the ceramic matrix, avoiding the weakness introduced by pore-forming additives.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent extracts the pore structure regulation function from the addition of pore formers and achieves it through control of sintering parameters and green body preparation. The pore structure is controlled by the formulation and molding method of the green body itself, combined with optimized sintering conditions, eliminating the need for separate pore-forming additives that would compromise mechanical strength.

Inventive Principle:
Principle #2Taking out (Extraction)

3Reliability

If multiple-step methods are used to prepare ceramic membranes with different pore structures, then surface properties are improved, but production cost increases

Engineering Contradiction:
Improvesurface propertiesVSAvoidproduction cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent merges multiple functions (pore structure formation, surface property modification, and mechanical strength optimization) into a single sintering process. By incorporating surface modification agents into the green body and controlling sintering parameters, the patent achieves multiple objectives simultaneously in one operation, eliminating the need for multiple separate treatment steps and reducing overall production cost.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent applies multi-functionality by designing a single sintering process that simultaneously achieves pore structure regulation, surface property modification, and mechanical strength optimization. The green body formulation and sintering conditions are optimized to perform multiple functions concurrently, making the process universally applicable for producing ceramic membranes with diverse properties without requiring multiple specialized treatment steps.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves high bending strength, efficient oil-water separation, and rapid emulsion preparation with regulated pore size and surface properties, reducing production costs and extending application fields.

Implementation Method 1

a sintering aid reacts in-situ at a high temperature with SiO2 generated by oxidation of a surface of SiC particles to form a tight neck connection among the SiC particles

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

carrying out in-situ sintering reaction according to a certain sintering procedure to obtain a SiC membrane

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 3

fully mixing the mixed powder B with a binder to obtain mixed powder C

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 4

putting the green body in a high temperature furnace, and carrying out in-situ sintering reaction

Methodology Applied
Scientific EffectHeating: Heating

Data Source

PatentUS20250222408A1Method for one-step regulation of a pore structure and surface properties of a silicon carbide (SIC) membrane
Publication Date: 2025.07.10 NANJING TECH UNIV
  • US20250222408A1 patent drawing
  • US20250222408A1 patent drawing
  • US20250222408A1 patent drawing

AI summary

The present invention relates to a method for one-step regulation of a pore structure and surface properties of a silicon carbide (SiC) membrane. The method comprises: first, fully mixing SiC powder with a sintering aid, and then synergistically regulating a pore structure and surface wetting properties of a SiC membrane by controlling a molding pressure and a sintering condition. The amount of SiO2 generated by oxidation of SiC is controlled, and in situ reaction of SiO2 and the sintering aid is prompted to generate a neck connection, such that a sintering temperature of the SiC membrane can be reduced, and the strength and corrosion resistance properties of the SiC membrane can also be improved. The degree of sintering of the SiC membrane is effectively controlled by means of the regulation of the molding pressure and the sintering temperature. It is a simple method for one-step regulation of a pore structure and surface properties of a SiC membrane. The SiC membrane prepared has porosity adjustable in a range of 13% to 48% and a pore size adjustable in a range of 0.17 μm to 1 μm; and the SiC membrane has an initial dynamic water contact angle in a range of 12.01° to 66.8° and an underwater oil contact angle adjustable in a range of 120.3° to 155.1°. The SiC membrane prepared has high bending strength and pure water permeation properties and show a broad application prospect in the field of oil-water separation and emulsion preparation.