Silicon Carbide Device 2-Layer Protective Film for Surface Flatness

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing methods for activation heat treatment of silicon carbide substrates often result in surface roughness due to insufficient protection, as conventional protective films like carbon films can crack or have inadequate thickness and quality, leading to vaporization of silicon atoms and subsequent surface roughness.

Innovation Solution

A 2-layer protective film structure is used, comprising a silicon film formed by sputtering in an argon gas atmosphere and a carbon or carbon nitride film, where the silicon film supplies atoms to prevent vaporization and the carbon film provides additional protection, with specific thicknesses and deposition conditions to ensure effective surface protection during high-temperature heat treatment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a carbon film is used as a protective film during activation heat treatment, then surface roughness is reduced, but the carbon film may crack or have insufficient thickness leading to vaporization of silicon atoms

Engineering Contradiction:
Improvesurface flatnessVSAvoidprotective film integrity
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent uses a composite protective film structure consisting of a carbon film layer and a silicon-rich silicon carbide layer. The carbon film provides surface protection while the silicon-rich layer prevents silicon atom vaporization. This composite structure combines the advantages of both materials to achieve both surface flatness and film integrity during high-temperature activation heat treatment.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The protective film is divided into two functional layers: an outer carbon film layer for surface protection and an inner silicon-rich silicon carbide layer for preventing silicon vaporization. This segmentation allows each layer to perform its specific function optimally, with the carbon layer providing chemical stability and the silicon-rich layer providing silicon atom replenishment during heat treatment.

Inventive Principle:
Principle #1Segmentation

2Quantity of substance

If activation heat treatment is performed at high temperature (1600-1800°C) without protective film, then impurity activation is achieved, but surface roughness occurs due to silicon atom vaporization

Engineering Contradiction:
Improveimpurity activationVSAvoidsurface flatness
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The protective film structure is formed in advance before the activation heat treatment process. The carbon film and silicon-rich silicon carbide layer are prepared beforehand to prevent silicon atom vaporization during the high-temperature treatment, ensuring both impurity activation and surface flatness are achieved simultaneously.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The silicon-rich silicon carbide layer acts as an intermediary between the silicon carbide substrate and the external environment during heat treatment. It supplies silicon atoms to the substrate surface, preventing silicon vaporization and maintaining surface flatness while allowing the heat treatment to proceed at the required high temperature for impurity activation.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If conventional single-layer carbon film is used, then deposition is simple, but film quality and thickness are insufficient to prevent silicon vaporization

Engineering Contradiction:
Improvefilm deposition simplicityVSAvoidsurface flatness
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

Instead of using a simple single-layer carbon film, the patent employs a composite structure with a carbon film layer and a silicon-rich silicon carbide layer. This composite approach maintains relative simplicity in the deposition process while significantly improving film quality and ability to prevent silicon vaporization during heat treatment.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The 2-layer protective film structure significantly suppresses surface roughness of silicon carbide substrates by preventing silicon atom vaporization and maintaining surface flatness, enhancing the reliability of silicon carbide semiconductor devices.

Implementation Method 1

a first protective film that is formed in the surface of the semiconductor substrate and supplies atoms that become insufficient in the semiconductor substrate consequent to heat treating

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

a second protective film that is formed in a surface of the first protective film and suppresses vaporization of silicon atoms from the first protective film

Methodology Applied
Scientific EffectVaporization suppression: Evaporation

Implementation Method 3

forming a protective film in the surface implanted with the impurity; the first protective film is formed by sputtering in an argon gas atmosphere

Methodology Applied
Scientific EffectSputtering: Sputtering

Data Source

PatentUS9748149B2Method of manufacturing a silicon carbide semiconductor device including forming a protective film with a 2-layer structure comprised of silicon and carbon
Publication Date: 2017.08.29 FUJI ELECTRIC CO LTD
  • US9748149B2 patent drawing
  • US9748149B2 patent drawing
  • US9748149B2 patent drawing

AI summary

A method of manufacturing a silicon carbide semiconductor device includes ion implanting an impurity into a surface of a semiconductor substrate comprised of silicon carbide, forming a protective film in the surface implanted with the impurity, and heat treating the semiconductor substrate covered by the protective film to activate the impurity. During formation of the protective film, the protective film has a 2-layer structure including a first protective film in the surface of the semiconductor substrate that supplies atoms that become insufficient in the semiconductor substrate as a result of the heat treating, and a second protective film in a surface of the first protective film that suppresses vaporization of silicon atoms from the first protective film. The first protective film may be a silicon film and the second protective film may be a carbon film or a carbon nitride film.