Defect-Free Silicon Carbide Substrate via Sacrificial Heteroepitaxy

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Solution Overview

Problem

Current semiconductor devices with silicon carbide (SiC) substrates face high defect densities and radiation vulnerability, particularly in aerospace applications, due to lattice mismatch and thermal expansion differences between SiC and Si, leading to reliability issues like single event burnout and increased threshold leakage current.

Innovation Solution

A method is developed to form a substantially defect-free SiC substrate using a sacrificial heteroepitaxy interface with inverted pyramid patterns and micropillars, followed by direct wafer bonding and removal of sacrificial layers, which confines defects to removable layers, reducing lattice mismatch and thermal stress, and enhances radiation hardness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If SiC layer is formed on Si substrate, then high breakdown voltage and high power density are achieved, but defect density increases due to lattice mismatch and thermal expansion differences

Engineering Contradiction:
Improvepower densityVSAvoiddefect density
Core Design Contradiction:
PowerVSManufacturing precision

Solution Approach 1:

A buffer layer is introduced between the Si substrate and the SiC layer to act as an intermediary that reduces lattice mismatch and thermal expansion differences. This buffer layer absorbs the mechanical stress and prevents defect propagation from the Si substrate to the SiC layer, enabling high power density devices with lower defect density.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The SiC layer is grown in multiple segments or stages with intermediate annealing and stress relief processes. By segmenting the growth process into controlled stages, the accumulated stress from lattice mismatch is periodically relieved, preventing the formation of large-scale defects while maintaining the high breakdown voltage characteristics.

Inventive Principle:
Principle #1Segmentation

2Ease of manufacture

If conventional SiC substrate methods are used, then manufacturing is simplified, but radiation hardness is insufficient for aerospace applications

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidradiation hardness
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The manufacturing process parameters are changed to include specific ion implantation doses, energy levels, and thermal annealing conditions that enhance radiation hardness. By modifying these process parameters, the SiC substrate gains improved resistance to radiation-induced defects while maintaining compatibility with conventional fabrication workflows.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Radiation hardening treatments are performed as preliminary actions during the manufacturing process, before the device is deployed in aerospace applications. Ion implantation and thermal annealing are applied in advance to pre-condition the SiC substrate, creating a more radiation-resistant structure that will withstand subsequent exposure to cosmic rays and radiation in space environments.

Inventive Principle:
Principle #10Preliminary action

3Reliability

If defect reduction techniques are applied to SiC substrate, then reliability improves, but manufacturing cost increases

Engineering Contradiction:
Improvesubstrate reliabilityVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

A sacrificial buffer layer is used that is intentionally designed to be removed after serving its purpose of reducing defects during growth. This disposable layer absorbs the cost of complex processing but eliminates the need for expensive permanent defect mitigation structures, ultimately reducing overall manufacturing costs while improving substrate reliability.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The buffer layer is discarded after fulfilling its defect-reduction function, and the process is recovered by directly growing the device layer on the cleaned substrate. This approach eliminates the need to maintain complex multi-layer structures throughout production, simplifying subsequent manufacturing steps and reducing costs while achieving high reliability through the temporary presence of the buffer layer during critical growth phases.

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in a nearly defect-free SiC substrate that is radiation hardened, improving reliability and reducing manufacturing costs, capable of withstanding high-energy radiation without permanent destructive effects, while maintaining low on-resistance and high breakdown voltage.

Implementation Method 1

forming a substantially defect-free SiC substrate using a sacrificial heteroepitaxy interface with inverted pyramid patterns and micropillars

Methodology Applied
Scientific EffectHeteroepitaxy: Epitaxy

Implementation Method 2

followed by direct wafer bonding and removal of sacrificial layers

Methodology Applied
Scientific EffectDirect wafer bonding: Welding

Data Source

PatentUS20230060866A1Semiconductor Device and Method of Forming Radiation Hardened Substantially Defect Free Silicon Carbide Substrate
Publication Date: 2023.03.02 ICEMOS TECH
  • US20230060866A1 patent drawing
  • US20230060866A1 patent drawing
  • US20230060866A1 patent drawing

AI summary

A semiconductor device has a first substrate and a first semiconductor layer having a first semiconductor material formed over the first substrate. A surface of the first semiconductor layer has a first element of the first semiconductor material. A first surface of a second semiconductor layer having the first semiconductor material is joined to the surface of the first semiconductor layer. The first surface of the second semiconductor layer has a second element of the first semiconductor material different from the first element. The first semiconductor material is silicon carbide or cubic silicon carbide. The first element is silicon or carbon, and the second element is carbon or silicon. The semiconductor device provides characteristics of radiation hardening. A third semiconductor layer is formed over a second surface of the second semiconductor layer opposite the first surface. An electrical component is formed over the second semiconductor layer.