SiC Substrate Etching with Si Vapor to Suppress Macro-Step Bunching

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Solution Overview

Problem

Conventional methods for manufacturing SiC substrates suffer from the formation of macro-step bunching, which adversely affects the characteristics and reliability of SiC semiconductor devices.

Innovation Solution

A method and device that utilize a main container generating vapor pressure of Si and C-containing gaseous species, with a temperature gradient and a Si vapor supply source, to etch the SiC substrate under a SiC--Si equilibrium vapor pressure environment, maintaining an atomic number ratio Si/C greater than 1, thereby suppressing macro-step bunching.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional etching methods are used on SiC substrate, then etching process can be completed, but macro-step bunching is formed on the substrate surface

Engineering Contradiction:
Improvesurface flatnessVSAvoiddevice reliability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The invention changes the chemical composition parameters of the etching atmosphere by introducing a Si vapor supply source, maintaining Si/C atomic ratio greater than 1, and controlling partial pressures of Si and C containing gaseous species. This parameter change modifies the etching chemistry to suppress macro-step bunching while maintaining etching capability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a controlled inert-like atmosphere by maintaining high Si vapor pressure relative to C vapor pressure (Si/C atomic ratio > 1). This specific atmospheric composition acts as a protective environment that prevents harmful macro-step bunching formation during the etching process.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Productivity

If step bunching is formed on SiC substrate surface, then etching process can proceed, but defects occur in the epitaxial growth layer

Engineering Contradiction:
Improveetching rateVSAvoidepitaxial layer quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The invention applies preliminary anti-action by introducing Si vapor before and during the etching process to prevent macro-step bunching formation. The Si vapor acts in advance to suppress the bunching mechanism, ensuring that the substrate surface remains suitable for subsequent high-quality epitaxial growth.

Inventive Principle:
Principle #9Preliminary anti-action

3Reliability

If conventional heat treatment is used to suppress step bunching, then step bunching is reduced, but complex equipment and high cost are required

Engineering Contradiction:
Improvesubstrate qualityVSAvoidequipment complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention introduces Si vapor as an intermediary substance that mediates the etching process. Instead of using complex heat treatment equipment, the Si vapor acts as a chemical mediator that suppresses macro-step bunching through controlled chemical interactions during etching, simplifying the overall process equipment requirements.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Manufacturing precision

If Si vapor supply is increased to suppress macro-step bunching, then surface quality is improved, but process control complexity increases

Engineering Contradiction:
Improvesurface flatnessVSAvoidprocess control
Core Design Contradiction:
Manufacturing precisionVSEase of operation

Solution Approach 1:

The invention establishes a clear parameter guideline (Si/C atomic ratio greater than 1) that simplifies process control. By focusing on maintaining this specific ratio through coordinated control of Si and C vapor pressures, the operation becomes more straightforward despite the additional Si vapor supply component.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively suppresses the formation of macro-step bunching, enhancing the quality and reliability of SiC substrates by reducing defects and improving the performance of semiconductor devices.

Implementation Method 1

a main container capable of accommodating a SiC substrate and configured to generate vapor pressure of a gaseous species containing Si element and a gaseous species containing C element in an internal space by heating

Methodology Applied
Scientific EffectVapor pressure generation: Vapour Pressure

Implementation Method 2

a heating furnace that accommodates the main container, generates vapor pressure of a gaseous species containing Si element in an internal space, and performs heating in a manner to form a temperature gradient

Methodology Applied
Scientific EffectTemperature gradient: Temperature Gradient

Implementation Method 3

a Si vapor supply source capable of supplying Si vapor into the main container

Methodology Applied
Scientific EffectVaporization: Evaporation

Implementation Method 4

by arranging and etching the SiC substrate and the Si vapor supply source in the main container that generates vapor pressure of the gaseous species containing Si element and the gaseous species containing the C element in the internal space by heating, it is possible to perform etching while suppressing formation of macro-step bunching

Methodology Applied
Scientific EffectChemical etching:

Data Source

PatentUS12451348B2Method and device for manufacturing sic substrate, and method for reducing macro-step bunching of sic substrate
Publication Date: 2025.10.21 TOYOTA TSUSHO CORP
  • US12451348B2 patent drawing
  • US12451348B2 patent drawing
  • US12451348B2 patent drawing

AI summary

A device for manufacturing a SiC substrate, in which formation of macro-step bunching is suppressed, comprises: a main body container that is capable of accommodating a SiC substrate and generates, by heating, a vapor pressure of gaseous species containing Si elements and gaseous species containing C elements, in an internal space; and a heating furnace that accommodates the main body container and performs heating so that a vapor pressure of the gaseous species containing Si elements is generated and a temperature gradient is formed, wherein the main body container has an etching space S1 and a Si vapor supply source capable of supplying Si vapor into the main body container, the etching space S1 being formed by making the SiC substrate face a portion of the main body container arranged on a lower-temperature side of the temperature gradient while the SiC substrate is disposed on a higher-temperature side of the temperature gradient.