Silicon Carbide Wafer Plasma Etching for Low-Roughness Epitaxy

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Solution Overview

Problem

The conventional manufacturing process of silicon carbide (SiC) wafers for epitaxial growth is time-consuming and risks damaging the surface due to the use of corrosive substances in chemical mechanical polishing (CMP) steps, limiting production rates and introducing defects.

Innovation Solution

A plasma etching method using an etch gas mixture comprising molecular hydrogen (H2), optionally with noble gases like argon and fluorine-bearing gases, to reduce surface roughness without the need for CMP, favoring the removal of defects and irregularities while maintaining a uniform crystalline structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If chemical mechanical polishing (CMP) is used to reduce surface roughness, then surface roughness is reduced to suitable levels for epitaxial growth, but the process becomes time-consuming and introduces risk of surface damage from corrosive substances

Engineering Contradiction:
Improvesurface roughnessVSAvoidproduction rate
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent replaces the chemical mechanical polishing (CMP) process with a plasma-based process using hydrogen-containing gas. This substitution eliminates the need for mechanical polishing and corrosive chemical slurries, thereby reducing processing time and eliminating surface damage risks while achieving the required surface roughness reduction for epitaxial growth

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fundamental parameter of the surface treatment process from mechanical/chemical removal (CMP) to plasma-based physical/chemical etching. By using hydrogen-containing plasma, the process achieves surface roughness reduction through controlled etching that removes defects and irregularities without the time-consuming and damaging effects of conventional CMP

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If chemical mechanical polishing (CMP) with corrosive substances is used, then surface roughness is reduced, but the surface and underlying crystal structure are at risk of damage

Engineering Contradiction:
Improvesurface roughnessVSAvoidsurface damage
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent replaces the chemical mechanical polishing (CMP) process with a plasma-based process using hydrogen-containing gas. This substitution eliminates the need for mechanical polishing and corrosive chemical slurries, thereby reducing processing time and eliminating surface damage risks while achieving the required surface roughness reduction for epitaxial growth

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent uses hydrogen-containing gas in a plasma state to create a controlled atmosphere for surface treatment. This plasma environment provides a non-corrosive alternative to traditional CMP slurries, achieving surface roughness reduction without introducing harmful corrosive substances that could damage the wafer surface or underlying crystal structure

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

3Manufacturing precision

If conventional multi-step processing is used, then surface roughness is reduced, but the process complexity and time consumption increase

Engineering Contradiction:
Improvesurface roughnessVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent merges multiple surface treatment functions (defect removal, roughness reduction, and surface preparation for epitaxial growth) into a single plasma processing step using hydrogen-containing gas. This consolidation eliminates the need for separate mechanical polishing and chemical mechanical polishing steps, thereby reducing process complexity while achieving the required surface quality

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent extracts and eliminates the chemical mechanical polishing (CMP) step from the conventional multi-step processing sequence. By using plasma-based surface treatment, the process removes the time-consuming and complex CMP operation while maintaining the essential function of surface roughness reduction and defect removal

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method significantly reduces surface roughness to values suitable for epitaxial growth, eliminating the need for CMP and enhancing production efficiency by ensuring a faster, more economical process with reduced risk of surface damage.

Implementation Method 1

generating a plasma from the etch gas mixture within the plasma processing chamber and using the plasma to etch the unmasked surface of the wafer

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

the adsorption of H2 molecules and/or hydrogen radicals onto the surface of the wafer alters the sputtering yield generated by ions from the plasma as they collide with the surface of the wafer

Methodology Applied
Scientific EffectSputtering: Sputtering

Implementation Method 3

the adsorption of H2 molecules and/or hydrogen radicals onto the surface of the wafer alters the sputtering yield generated by ions from the plasma

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS20230326735A1Method of preparing a silicon carbide wafer
Publication Date: 2023.10.12 OXFORD INSTR NANOTECHNOLOGY TOOLS LTD
  • US20230326735A1 patent drawing
  • US20230326735A1 patent drawing
  • US20230326735A1 patent drawing

AI summary

A method of preparing a silicon carbide wafer for subsequent epitaxial growth thereon is disclosed. The method comprises (a) placing the silicon carbide wafer onto a support table in a plasma processing chamber such that the surface of the silicon carbide wafer distal to the support table is unmasked; (b) establishing a flow of an etch gas mixture into the plasma processing chamber, wherein the etch gas mixture comprises molecular hydrogen, H2; and (c) generating a plasma from the etch gas mixture within the plasma processing chamber and using the plasma to etch the unmasked surface of the wafer so as to reduce the roughness of the unmasked surface.