SiCN Interconnect Insulator Composition to Prevent Peeling and Diffusion

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Solution Overview

Problem

Existing insulators on semiconductor interconnects often peel or crack, leading to undesirable characteristics such as increased capacitance and diffusion of metal atoms.

Innovation Solution

A semiconductor device is developed with a SiCN film as the second insulator, where the content of Si—H groups is 6.0% or less and the content of Si—CH3 groups is 0.5% or less, to improve adhesion and reduce capacitance while preventing metal atom diffusion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If an insulator is formed on the interconnect to prevent metal atom diffusion, then metal atom diffusion is prevented, but the insulator may peel from the contacting interconnect or other insulators causing cracks

Engineering Contradiction:
Improvemetal atom diffusion preventionVSAvoidinsulator adhesion
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent changes the chemical composition parameters of the insulator by controlling the content of Si-H groups to 6.0% or less and Si-CH3 groups to 0.5% or less. This parameter optimization improves the adhesion between the insulator and interconnect while maintaining the diffusion prevention function, thereby resolving the contradiction between reliability and strength.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If a conventional insulator is used on the interconnect, then metal atom diffusion is prevented, but the capacitance increases due to peeling and cracking

Engineering Contradiction:
Improvemetal atom diffusion preventionVSAvoidcapacitance
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

By optimizing the chemical composition parameters (Si-H groups ≤6.0%, Si-CH3 groups ≤0.5%), the patent prevents insulator peeling and cracking. This maintains the integrity of the insulator layer, thereby reducing parasitic capacitance while preserving the metal atom diffusion prevention capability.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If the insulator is formed with conventional composition, then it provides basic insulation, but it shows undesirable characteristics such as peeling and cracking

Engineering Contradiction:
Improveinsulator formationVSAvoidinsulator integrity
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent applies parameter changes by precisely controlling the chemical composition of the insulator material. By limiting Si-H groups to 6.0% or less and Si-CH3 groups to 0.5% or less, the insulator maintains its structural integrity and prevents peeling and cracking, thereby improving reliability while maintaining proper insulation function.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS12230538B2Semiconductor device and method of manufacturing the same
Publication Date: 2025.02.18 KIOXIA CORP
  • US12230538B2 patent drawing
  • US12230538B2 patent drawing
  • US12230538B2 patent drawing

AI summary

In one embodiment, the semiconductor device includes a first insulator including Si (silicon) and O (oxygen). The device further includes a first interconnect provided in the first insulator and including a metal element. The device further includes a second insulator provided on the first insulator and the first interconnect and including Si, C (carbon) and N (nitrogen), content of Si—H groups (H represents hydrogen) in the second insulator being 6.0% or less, content of Si—CH3 groups in the second insulator being 0.5% or less. The device further includes a second interconnect provided on the first interconnect in the second insulator and including the metal element.