SiGe Imaging Surface Structure for Defect-Free IR Light Capture

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Solution Overview

Problem

Current techniques face challenges in producing silicon germanium substrates without defects like dislocations or mosaic structures, which can lead to uneven structure formation issues during etching, resulting in dents or cracks in solid-state imaging devices.

Innovation Solution

A solid-state imaging device with a substrate and light incident surface layer made of a compound semiconductor containing germanium, where the germanium concentration increases towards the surface, allowing for the formation of a tapered bump structure through crystalline anisotropic and isotropic etching, enabling defect-free uneven structure formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If an uneven structure is formed on a light incident surface of a substrate including silicon germanium using crystalline anisotropic etching, then the quantum efficiency in the infrared region can be increased, but there is a possibility that an etching solution enters a defect of the silicon germanium and thus the uneven structure has a dent or a crack

Engineering Contradiction:
Improvequantum efficiency in infrared regionVSAvoiddefect-free uneven structure
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by forming a protective film on the light incident surface of the silicon germanium substrate before performing crystalline anisotropic etching. This protective film prevents the etching solution from entering defects such as dislocations and mosaic structures, thereby avoiding the formation of dents or cracks while still allowing the uneven structure to be formed for enhancing infrared quantum efficiency.

Inventive Principle:
Principle #10Preliminary action

2Manufacturing precision

If a protective film is formed on the light incident surface before etching, then the uneven structure can be formed without dents or cracks, but the production process becomes more complex

Engineering Contradiction:
Improvedefect-free uneven structureVSAvoidproduction process
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by selecting a protective film material with specific properties (such as silicon oxide or silicon nitride) and controlling its thickness and formation conditions. By optimizing these parameters, the protective film effectively prevents etching solution penetration while minimizing the added complexity to the production process. The film is removed after etching, leaving the desired uneven structure without dents or cracks.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for the easy formation of a tapered bump structure on the light incident surface of a silicon germanium substrate, enhancing quantum efficiency in the infrared region by increasing the optical path length and reducing defects in the imaging device.

Implementation Method 1

a substrate in which a plurality of photoelectric conversion parts is formed

Methodology Applied
Scientific EffectPhotoelectric conversion: Photoelectric Effect

Implementation Method 2

forming a groove having a lattice shape in the light incident surface layer by performing crystalline anisotropic etching on the light incident surface layer

Methodology Applied
Scientific EffectCrystalline anisotropic etching: Anisotropy

Data Source

PatentUS20240030267A1Solid-state imaging device, electronic apparatus and solid-state imaging device production method
Publication Date: 2024.01.25 SONY SEMICON SOLUTIONS CORP
  • US20240030267A1 patent drawing
  • US20240030267A1 patent drawing
  • US20240030267A1 patent drawing

AI summary

A solid-state imaging device is provided with a substrate in which a plurality of photoelectric conversion parts is formed, and with a light incident surface layer formed on the light incident surface of the substrate. The substrate and the light incident surface layer include a compound semiconductor containing germanium. A concentration of the germanium in the light incident surface layer increases toward a surface side remote from the substrate. At the time of production, isotropic etching is performed after a lattice-shaped groove is formed in the light incident surface layer, so that a groove width of the lattice-shaped groove increases toward a light incident surface side of the light incident surface layer due to a difference in etching rate attributed to the concentration of the germanium, and an uneven structure having a tapered bump can thus be formed relatively easily.