Silane-Based Benzocarbazole Compound for OLED Emission Layer

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current organic light-emitting devices (OLEDs) face challenges in achieving high electrical stability, efficient charge transport, and improved emission characteristics, particularly in blue emission, due to limitations in the materials used in their emission layers.

Innovation Solution

A silane-based compound with a benzocarbazole group is introduced, which enhances electrical stability, charge transport, and blue emission characteristics, and can be used as a host for phosphorescent or fluorescent dopants for red, green, blue, and white emissions, improving the overall performance of OLEDs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional materials are used in OLED emission layers, then device structure can be kept simple, but electrical stability and charge transport efficiency are insufficient

Engineering Contradiction:
Improveelectrical stabilityVSAvoidmaterial structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs composite material design by combining silane backbone structure with benzocarbazole functional groups and various substituent moieties. This composite approach creates molecules that simultaneously achieve high electrical stability, efficient charge transport, and improved emission characteristics, resolving the contradiction between reliability improvement and structural complexity

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional emission layer materials are used, then manufacturing process remains simple, but charge transport efficiency and emission characteristics are limited

Engineering Contradiction:
Improvecharge transport efficiencyVSAvoidcompound structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent systematically varies molecular parameters including substituent types (electron-donating or electron-withdrawing groups), substituent positions, and silane backbone configurations to optimize charge transport efficiency and emission characteristics. This parameter optimization approach enables improved productivity without requiring fundamentally complex manufacturing processes

Inventive Principle:
Principle #35Parameter changes

3Power

If standard OLED materials are used, then device complexity is low, but emission efficiency and luminance performance are insufficient

Engineering Contradiction:
ImproveluminanceVSAvoidmaterial composition complexity
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The patent applies local quality principle by introducing specific functional groups (benzocarbazole) at strategic positions within the silane-based molecular structure. These localized functional modifications enhance electron-hole recombination efficiency and luminance output without requiring complete redesign of the entire device architecture, thus improving power performance while controlling complexity

Inventive Principle:
Principle #3Local quality

4Duration of action of stationary object

If conventional materials are used in OLEDs, then device structure is simple, but lifetime and power consumption characteristics are poor

Engineering Contradiction:
Improvedevice lifetimeVSAvoidcompound structure complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent inverts the conventional approach by using silane-based compounds with benzocarbazole groups as the core emission layer material rather than using traditional rigid aromatic hydrocarbons. This inversion of material selection strategy fundamentally improves device lifetime and power consumption characteristics while the modular molecular design keeps the overall device structure relatively simple

Inventive Principle:
Principle #13The other way round (Inversion)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The silane-based compound with a benzocarbazole group improves the electrical stability, charge transport, and emission efficiency of OLEDs, leading to higher luminance, lower power consumption, and extended lifetime, while also providing improved blue emission characteristics.

Implementation Method 1

enhances electrical stability, charge transport, and blue emission characteristics

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 2

Carriers (e.g., the holes and electrons) may recombine in the emission layer to generate exitons. When the exitons drop from an excited state to a ground state, light is emitted.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9660204B2Silane-based compound and organic light-emitting device including the same
Publication Date: 2017.05.23 SAMSUNG DISPLAY CO LTD
  • US9660204B2 patent drawing
  • US9660204B2 patent drawing
  • US9660204B2 patent drawing

AI summary

A silane-based compound and an organic light-emitting device including the same, the compound being represented by Formula 1: