Silane-Coated Acid Chloride Masterbatch for Polymer Additives

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Solution Overview

Problem

Inorganic acid chlorides, such as stannous chloride, pose handling challenges due to corrosiveness and dust formation, and high loadings in masterbatches lead to reduced encapsulation efficiency and flow issues in polymer processing.

Innovation Solution

An organosilane-coated acid chloride masterbatch is developed, where the acid chloride is combined with a silane compound to form a stable, non-corrosive and dust-reduced pellet form suitable for polymer processing, utilizing a polymer matrix to enhance handling and flow characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If high loadings of acid chloride additive are included in the masterbatch, then the additive concentration is improved, but the encapsulation ability of the masterbatch polymer reduces and dusting increases

Engineering Contradiction:
Improveadditive concentrationVSAvoiddusting
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The acid chloride additive is nested within the masterbatch polymer matrix, which is then incorporated into the final polymer product. This nested structure allows high concentrations of the additive to be contained within protective polymer layers, preventing dusting while maintaining additive availability.

Inventive Principle:
Principle #7Nested doll (Nesting)

Solution Approach 2:

A composite masterbatch material is created by combining the acid chloride additive with a polymer matrix. This composite structure provides both the high additive concentration needed for effectiveness and the polymer encapsulation needed to prevent dusting and improve handling safety.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If high loadings of acid chloride additive are included in the masterbatch, then the additive concentration is improved, but the flow characteristics of the masterbatch deteriorate

Engineering Contradiction:
Improveadditive concentrationVSAvoidflow characteristics
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The masterbatch is processed at controlled temperatures and shear rates during extrusion to optimize flow characteristics. By adjusting processing parameters, the system achieves both high additive loading and adequate flow properties for handling and injection molding.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If acid chloride masterbatch is handled manually, then the handling simplicity is improved, but corrosivity and health safety problems worsen

Engineering Contradiction:
Improvehandling simplicityVSAvoidcorrosivity
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The acid chloride additive is encapsulated within thin polymer matrix layers in the masterbatch pellets. This protective shell prevents direct contact between the corrosive additive and handlers, enabling safe manual handling while maintaining the reactive properties needed for the application.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The masterbatch is designed as a ready-to-use, single-stage product that eliminates the need for separate handling of the corrosive acid chloride. The polymer encapsulation provides temporary protection during handling and storage, with the additive releasing its function only when needed in the final polymer processing stage.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The silane-coated acid chloride masterbatch reduces corrosivity, improves flow characteristics, and allows for safer and more efficient introduction into polymer production processes, minimizing acid release and dust formation, while maintaining high additive concentrations.

Implementation Method 1

the acid chloride is combined with a silane compound to form a stable, non-corrosive and dust-reduced pellet form

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS10047226B2Provision of inorganic powders with reduced hazard
Publication Date: 2018.08.14 WILLIAM BLYTHE & CO LTD
  • US10047226B2 patent drawing

AI summary

Provision of inorganic powders with reduced hazard: acid chlorides which have use in polymer production can be incorporated into a masterbatch with the addition of a silane compound to reduce the corrosiveness of the masterbatch pellets and reduce variability of pellet size. This presents advantages in transport and handling costs and facilitates downstream processing.