Silane Coupling Agent for Wire Grid Pattern Manufacturing

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Solution Overview

Problem

In the nano-imprint lithography process for manufacturing wire grid patterns, there is a challenge in preventing the stripping of resin patterns during stamp removal and efficiently removing defective resin patterns, which affects pattern precision and processibility, especially as pattern size increases.

Innovation Solution

A method involving a laminate structure with a base member, a metal layer, a mask layer containing metal oxide, an adhesive layer with a silane coupling agent, and a patterned resin layer, where the laminate is treated with light and acid to form and remove the resin pattern effectively, using silane coupling agents represented by specific chemical formulas to enhance bonding and facilitate rework processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a conventional nano-imprint lithography process is used to form wire grid patterns, then the process can manufacture large-size patterns cost-effectively, but the resin pattern is stripped together with the stamp during removal, causing incomplete pattern formation

Engineering Contradiction:
Improvecost-effectiveness of large-size pattern manufacturingVSAvoidpattern formation completeness
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent introduces a release layer as an intermediary between the stamp and the resin layer. This release layer prevents direct adhesion between the stamp and resin pattern, allowing the stamp to be removed without stripping the resin pattern. The release layer acts as a mediator that enables clean separation while maintaining pattern integrity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the surface energy parameters of the stamp and release layer by applying specific coatings. By controlling the surface energy characteristics, the adhesive force between the stamp and release layer is optimized to be stronger than the force between the release layer and resin pattern, preventing resin stripping during stamp removal.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If the pattern size precision is increased, then the wire grid pattern achieves higher precision, but the resin pattern stripping problem becomes more serious during stamp removal

Engineering Contradiction:
Improvepattern size precisionVSAvoidresin pattern retention during stamp removal
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The release layer serves as a protective intermediary that is particularly crucial for high-precision patterns. It prevents mechanical stress and adhesion forces during stamp removal from directly affecting the delicate, high-precision resin pattern, thereby maintaining both pattern integrity and precision.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The release layer provides beforehand cushioning by being pre-applied to the stamp surface. This cushioning layer absorbs and distributes the mechanical stresses during stamp removal, preventing direct transmission of damaging forces to the high-precision resin pattern.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Ease of repair

If a rework process is performed to remove defective resin patterns, then additional processing capability is provided, but the defective resin pattern cannot be completely removed and foreign matter remains

Engineering Contradiction:
Improverework capabilityVSAvoidforeign matter contamination
Core Design Contradiction:
Ease of repairVSManufacturing precision

Solution Approach 1:

The release layer acts as a removable intermediary that facilitates complete resin pattern removal during rework. By controlling the adhesion characteristics of the release layer, the resin pattern can be completely detached from the substrate without leaving foreign matter, enabling clean rework operations.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Manufacturing precision

If the resin layer is strongly bonded to the stamp during imprinting, then the pattern transfer is improved, but the resin pattern is stripped during stamp removal

Engineering Contradiction:
Improvepattern transfer qualityVSAvoidresin pattern adhesion to stamp
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The release layer is positioned between the stamp and resin layer, creating a controlled adhesion interface. The release layer maintains sufficient adhesion to the resin for pattern transfer while providing a release mechanism that prevents permanent bonding, allowing stamp removal without resin stripping.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent controls the adhesion parameters by selecting materials with appropriate surface energy characteristics. The release layer is designed to have intermediate adhesion strength - strong enough to transfer the pattern but weak enough to allow clean separation during stamp removal.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method prevents resin pattern stripping during stamp removal and enables easy removal of defective patterns, improving the precision and efficiency of wire grid pattern manufacturing by maintaining strong bonds between layers and allowing for effective rework without additional metal or mask layers.

Implementation Method 1

The silane coupling agent may include a compound represented by Chemical Formula 1-1, Chemical Formula 2-1, or Chemical Formula 3-1

Methodology Applied
Scientific EffectCovalent bonding: Chemical Bonding

Implementation Method 2

the resin layer may include a photoinitiator and a (meth)acrylate-based monomer or oligomer

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 3

the adhesive layer may be irradiated with ultraviolet light to denature the silane coupling agent, thereby making it easy to remove the resin pattern

Methodology Applied
Scientific EffectChemical decomposition: Decomposition (biological)

Data Source

PatentUS10732503B2Silane coupling agent and method of manufacturing wire grid pattern using the same
Publication Date: 2020.08.04 SAMSUNG DISPLAY CO LTD
  • US10732503B2 patent drawing
  • US10732503B2 patent drawing
  • US10732503B2 patent drawing

AI summary

A method of manufacturing a wire grid pattern includes providing a laminate having a base member, a metal layer disposed on the base member, a mask layer disposed on the metal layer and containing a metal oxide, an adhesive layer disposed on the mask layer, and a patterned resin layer disposed on the adhesive layer and formed by irradiation of first light; and irradiating the laminate with second light. The adhesive layer may comprise a silane coupling agent.