Silane-Coated Glass Backlight for PMMA Adhesion

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Solution Overview

Problem

Conventional methods for printing light extraction features on glass light guide plates face challenges due to insufficient adhesion of PMMA chemistry to bare glass surfaces, leading to delamination during weathering tests and contamination issues, which affect the reliability and uniformity of printed patterns.

Innovation Solution

A glass substrate is coated with 3-mercaptopropyl trimethoxysilane, aminopropyl triethoxysilane, or silanated PMMA, followed by the deposition of PMMA-containing light extraction dots, promoting strong adhesion and resistance to delamination and contamination, while maintaining optical performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If PMMA chemistry is used to print light extraction features on glass light guide plates, then the manufacturing process can be maintained, but the adhesion is insufficient leading to delamination

Engineering Contradiction:
Improvemanufacturing process compatibilityVSAvoidadhesion reliability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

A silane-based coupling agent is applied as an intermediary layer between the glass substrate and PMMA light extraction features. The silane chemistry provides both glass surface bonding and PMMA compatibility, serving as a mediator that enables adhesion between the two incompatible materials without changing the existing PMMA printing process

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The surface chemistry parameters of the glass substrate are modified by applying silane treatment, which changes the surface energy and chemical composition to be more compatible with PMMA. This parameter change enables the PMMA chemistry to adhere properly to the glass surface while maintaining the same printing process

Inventive Principle:
Principle #35Parameter changes

2Strength

If glass substrates are used instead of polymer light guide plates, then mechanical properties are improved, but adhesion of printed features deteriorates

Engineering Contradiction:
Improvemechanical propertiesVSAvoidadhesion of printed features
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The silane coupling agent acts as an intermediary that bridges the glass substrate and PMMA features, allowing glass to provide superior mechanical properties while the silane layer ensures reliable adhesion of printed features through its dual compatibility with both glass and polymer

Inventive Principle:
Principle #24Intermediary (Mediator)

3Device complexity

If light extraction features are printed directly on bare glass, then the process is simple, but contamination and delamination occur during weathering

Engineering Contradiction:
Improveprocess complexityVSAvoidcontamination and delamination
Core Design Contradiction:
Device complexityVSObject-affected harmful factors

Solution Approach 1:

The silane coupling agent is applied in advance as a preparatory step before printing the light extraction features. This preliminary action creates a protective and adhesive surface layer that prevents contamination and delamination during subsequent weathering and handling

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The silane layer serves as a protective intermediary between the glass substrate and the printed features, shielding against environmental contaminants and preventing delamination during weathering tests while maintaining process simplicity

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution ensures reliable adhesion of PMMA ink to glass surfaces, preventing delamination and contamination, and maintaining optical performance even after exposure to harsh conditions, such as high temperature and humidity, and solvent abrasion.

Implementation Method 1

the coating can be covalently bonded to the first major surface

Methodology Applied
Scientific EffectCovalent bonding: Chemical Bonding

Implementation Method 2

A glass substrate is coated with 3-mercaptopropyl trimethoxysilane, aminopropyl triethoxysilane, or silanated PMMA, followed by the deposition of PMMA-containing light extraction dots, promoting strong adhesion

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS11885998B2Method of treating a glass surface and treated glass articles
Publication Date: 2024.01.30 CORNING INC
  • US11885998B2 patent drawing
  • US11885998B2 patent drawing
  • US11885998B2 patent drawing

AI summary

A display backlight unit is disclosed including a glass substrate with a first major surface and a second major surface opposite the first major surface, the first major surface coated with at least one of 3-mercaptopropyl trimethoxysilane, aminopropyl triethoxysilane, or silanated PMMA, and a plurality of PMMA-containing light extraction dots deposited on the coated first major surface.