Silazane-Based Encapsulation Films for Flexible OLED Moisture Blocking

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing OLED device packaging methods fail to effectively isolate the device from moisture and oxygen, leading to degradation of organic materials and reduced lifespan due to pinholes in inorganic layers and poor moisture/oxygen blocking by polymer films.

Innovation Solution

A silicon-containing encapsulation film composition using a silazane compound is developed, which forms a high-purity film with low impurity content, blocking moisture and oxygen through deposition at low temperatures using silazane compounds represented by Chemical Formulas 1 and 2, allowing for silicon oxide or silicon nitride films with improved deposition rates and durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional glass substrate packaging is used, then chemical stability and electrical insulation are improved, but device flexibility and thickness are worsened

Engineering Contradiction:
Improvechemical stabilityVSAvoidflexibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent replaces rigid glass substrates with thin film encapsulation layers (silicon oxide, silicon nitride, or organic polymer films) that can be deposited directly on flexible substrates like PET or PEN. This enables the OLED device to achieve flexibility while maintaining protection through multiple thin film layers totaling 1-5 micrometers thickness, dramatically reducing both thickness and improving adaptability compared to traditional glass packaging.

Inventive Principle:
Principle #30Flexible shells and thin films

2Volume of stationary object

If inorganic thin film encapsulation is used, then compactness is improved, but pinhole formation and moisture permeation are worsened

Engineering Contradiction:
Improveencapsulation thicknessVSAvoidmoisture blocking ability
Core Design Contradiction:
Volume of stationary objectVSReliability

Solution Approach 1:

The patent employs composite encapsulation structures combining multiple inorganic layers (silicon oxide, silicon nitride) with organic polymer layers. This multi-layer composite approach creates a synergistic effect where each layer compensates for the weaknesses of others, preventing pinhole formation and moisture permeation while maintaining thin overall thickness. The combination achieves superior moisture blocking capability compared to single-material encapsulation.

Inventive Principle:
Principle #40Composite materials

3Adaptability or versatility

If polymer thin film encapsulation is used, then flexibility is improved, but moisture and oxygen blocking ability is worsened

Engineering Contradiction:
ImproveflexibilityVSAvoidmoisture blocking ability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent combines organic polymer films (providing flexibility) with inorganic thin film layers (providing superior moisture and oxygen blocking). The inorganic layers act as barriers to permeation while the polymer layers maintain flexibility and provide stress relief. This composite structure achieves both flexibility and excellent moisture blocking ability, overcoming the limitations of pure polymer encapsulation.

Inventive Principle:
Principle #40Composite materials

4Reliability

If multiple encapsulation layers are added to improve protection, then moisture blocking is improved, but device complexity and manufacturing difficulty are worsened

Engineering Contradiction:
Improvemoisture blocking abilityVSAvoidencapsulation structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses silane-based precursor materials that can form multiple protective functions through a single deposition process. The silane compounds can simultaneously create silicon oxide, silicon nitride, or hybrid layers depending on processing conditions, providing moisture blocking, mechanical protection, and stress management in one encapsulation step. This reduces manufacturing complexity compared to depositing multiple separate layers with different materials.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The silicon-containing encapsulation film effectively prevents moisture and oxygen permeation, maintaining the integrity and extending the lifespan of OLED devices by providing high-purity, durable films with low water vapor transmission rates.

Implementation Method 1

a method for manufacturing a silicon-containing encapsulation film using the same

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 2

forming a thin film having a dense structure

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 3

forming a thin film having a dense structure

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentUS20250250462A1Silicon-bearing encapsulation film composition including silazane compound and method for manufacturing silicon-bearing encapsulation film using same
Publication Date: 2025.08.07 DNF
  • US20250250462A1 patent drawing
  • US20250250462A1 patent drawing
  • US20250250462A1 patent drawing

AI summary

The present invention provides a silicon-bearing encapsulation film composition including a silazane compound and a method for manufacturing a silicon-bearing film using same, wherein the film blocks moisture and oxygen to prevent the deterioration of organic light-emitting diodes. The silicon-bearing encapsulation film composition according to the present invention can exhibit an excellent deposition rate due to the high vapor pressure thereof, and can provide a high-quality silicon-bearing encapsulation film with high purity and high durability.