Silazane-Based Encapsulation Films for Flexible OLED Moisture Blocking
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Solution Overview
Problem
Existing OLED device packaging methods fail to effectively isolate the device from moisture and oxygen, leading to degradation of organic materials and reduced lifespan due to pinholes in inorganic layers and poor moisture/oxygen blocking by polymer films.
Innovation Solution
A silicon-containing encapsulation film composition using a silazane compound is developed, which forms a high-purity film with low impurity content, blocking moisture and oxygen through deposition at low temperatures using silazane compounds represented by Chemical Formulas 1 and 2, allowing for silicon oxide or silicon nitride films with improved deposition rates and durability.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If traditional glass substrate packaging is used, then chemical stability and electrical insulation are improved, but device flexibility and thickness are worsened
Solution Approach 1:
The patent replaces rigid glass substrates with thin film encapsulation layers (silicon oxide, silicon nitride, or organic polymer films) that can be deposited directly on flexible substrates like PET or PEN. This enables the OLED device to achieve flexibility while maintaining protection through multiple thin film layers totaling 1-5 micrometers thickness, dramatically reducing both thickness and improving adaptability compared to traditional glass packaging.
2Volume of stationary object
If inorganic thin film encapsulation is used, then compactness is improved, but pinhole formation and moisture permeation are worsened
Solution Approach 1:
The patent employs composite encapsulation structures combining multiple inorganic layers (silicon oxide, silicon nitride) with organic polymer layers. This multi-layer composite approach creates a synergistic effect where each layer compensates for the weaknesses of others, preventing pinhole formation and moisture permeation while maintaining thin overall thickness. The combination achieves superior moisture blocking capability compared to single-material encapsulation.
3Adaptability or versatility
If polymer thin film encapsulation is used, then flexibility is improved, but moisture and oxygen blocking ability is worsened
Solution Approach 1:
The patent combines organic polymer films (providing flexibility) with inorganic thin film layers (providing superior moisture and oxygen blocking). The inorganic layers act as barriers to permeation while the polymer layers maintain flexibility and provide stress relief. This composite structure achieves both flexibility and excellent moisture blocking ability, overcoming the limitations of pure polymer encapsulation.
4Reliability
If multiple encapsulation layers are added to improve protection, then moisture blocking is improved, but device complexity and manufacturing difficulty are worsened
Solution Approach 1:
The patent uses silane-based precursor materials that can form multiple protective functions through a single deposition process. The silane compounds can simultaneously create silicon oxide, silicon nitride, or hybrid layers depending on processing conditions, providing moisture blocking, mechanical protection, and stress management in one encapsulation step. This reduces manufacturing complexity compared to depositing multiple separate layers with different materials.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The silicon-containing encapsulation film effectively prevents moisture and oxygen permeation, maintaining the integrity and extending the lifespan of OLED devices by providing high-purity, durable films with low water vapor transmission rates.
Implementation Method 1
a method for manufacturing a silicon-containing encapsulation film using the same
Implementation Method 2
forming a thin film having a dense structure
Implementation Method 3
forming a thin film having a dense structure
Data Source
AI summary
The present invention provides a silicon-bearing encapsulation film composition including a silazane compound and a method for manufacturing a silicon-bearing film using same, wherein the film blocks moisture and oxygen to prevent the deterioration of organic light-emitting diodes. The silicon-bearing encapsulation film composition according to the present invention can exhibit an excellent deposition rate due to the high vapor pressure thereof, and can provide a high-quality silicon-bearing encapsulation film with high purity and high durability.


