Silazane Phosphor Coating for Precise Micro-LED Color Curing

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Solution Overview

Problem

Current manufacturing processes for optoelectronic devices, such as LEDs and micro-LEDs, face challenges in achieving uniform and stable color distribution and temperature due to variations in wavelength converting materials, leading to inconsistent color points and thermal stress issues during high-temperature curing.

Innovation Solution

A process involving multiple layers of a formulation containing a silazane polymer and wavelength converting materials, where each layer is precured using radiation and then cured with heat or radiation, allowing for precise control of color point and reduced thermal stress through lower temperature curing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If high temperature curing is used to cure the wavelength converting material layer, then the curing speed is improved, but thermal stress and damage to the LED precursor increases

Engineering Contradiction:
Improvecuring speedVSAvoidthermal stress
Core Design Contradiction:
SpeedVSObject-affected harmful factors

Solution Approach 1:

The curing process is divided into multiple sequential curing steps rather than a single high-temperature step. Each layer is cured individually at controlled temperatures, allowing the thermal stress to be distributed and managed throughout the manufacturing process, thus preventing damage to the LED precursor while maintaining efficient curing speed.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The wavelength converting material layer is applied and prepared on the LED precursor before the final curing step. This preliminary positioning allows for optimized curing conditions to be applied subsequently, reducing the need for excessive heat during the actual curing process and thereby minimizing thermal stress on the precursor.

Inventive Principle:
Principle #10Preliminary action

2Manufacturing precision

If multiple wavelength converting materials are used to achieve desired color point, then color precision is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvecolor point precisionVSAvoidmanufacturing process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The manufacturing process segments the application and curing of different wavelength converting materials into separate, sequential steps. Each material layer is applied and cured independently, which simplifies the control of each individual step while achieving the desired overall color precision through the combination of multiple layers with different emission characteristics.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different wavelength converting materials are applied to different regions or layers of the LED device, with each material optimized for specific color coordinates. This local optimization allows precise control of the overall color point by combining materials with complementary emission properties, achieving high color precision without requiring all materials to be processed simultaneously.

Inventive Principle:
Principle #3Local quality

3Stability of the object's composition

If uniform coating of wavelength converting materials is achieved, then color uniformity is improved, but manufacturing time increases

Engineering Contradiction:
Improvecolor uniformityVSAvoidmanufacturing throughput
Core Design Contradiction:
Stability of the object's compositionVSProductivity

Solution Approach 1:

The coating and curing process is segmented into multiple thin layers rather than applying a single thick layer. Each thin layer can be coated more uniformly and cured quickly, reducing the time required per layer. The cumulative effect of multiple uniformly coated layers achieves the desired overall color uniformity while the total manufacturing time remains manageable due to the reduced curing time per layer.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method results in optoelectronic devices with improved barrier properties, enhanced color point stability, and better mechanical and thermal stability, enabling cost-effective and efficient large-scale production with precise color adjustment.

Implementation Method 1

precured by exposure to radiation

Methodology Applied
Scientific EffectRadiation curing: Photopolymerisation

Implementation Method 2

cured by exposure to heat or radiation

Methodology Applied
Scientific EffectThermal curing: Heat Treatment

Implementation Method 3

wavelength converting materials such as e.g. phosphors or semiconductor nanoparticles (quantum materials) are used

Methodology Applied
Scientific EffectWavelength conversion: Photoluminescence

Data Source

PatentUS11888095B2Manufacturing process for an optoelectronic device
Publication Date: 2024.01.30 MERCK PATENT GMBH
  • US11888095B2 patent drawing
  • US11888095B2 patent drawing
  • US11888095B2 patent drawing

AI summary

The present invention relates to a process for manufacturing an optoelectronic device, wherein a layer of a formulation containing a silazane polymer and a wavelength converting material is applied to an optoelectronic device precursor, precured by exposure to radiation and then cured. There is further provided an optoelectronic device, preferably a light emitting device (LED) or a micro-light emitting device (micro-LED), which is prepared by said manufacturing process.