Silica-Coupled Tire Rubber Composition for Wear and Wet Grip

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Solution Overview

Problem

The existing rubber composition for tires has poor processability and fails to meet modern standards for wear resistance and wet performance, leading to a trade-off between energy efficiency and gripping force in pneumatic tires.

Innovation Solution

A rubber composition comprising diene rubber with specific conjugated diene rubber, silica with a predetermined CTAB adsorption specific surface area, and a silane coupling agent, which enhances the interaction between the rubber and silica, improving processability and reinforcing the tire's wear resistance and wet performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional rubber composition is used, then manufacturing simplicity is maintained, but processability deteriorates and performance (wear resistance and wet performance) is insufficient

Engineering Contradiction:
Improvewear resistance and wet performanceVSAvoidprocessability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies parameter changes by precisely controlling the glass transition temperature (not lower than -40°C) and the specific composition ratios of copolymer rubber components. By adjusting these physical and chemical parameters within defined ranges, the invention achieves optimal balance between processability and performance characteristics such as wear resistance and wet performance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite materials by combining copolymer rubber obtained by copolymerizing 1,3-butadiene and styrene with other diene rubber in specific ratios (not less than 50 wt.% copolymer rubber and not greater than 50 wt.% other diene rubber). This composite approach allows the material to exhibit both good processability and enhanced wear resistance and wet performance.

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If silica and carbon black are added to improve wear resistance, then durability is enhanced, but processing complexity increases

Engineering Contradiction:
Improvewear resistanceVSAvoidcomposition complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by precisely controlling the glass transition temperature (not lower than -40°C) and the specific composition ratios of copolymer rubber components. By adjusting these physical and chemical parameters within defined ranges, the invention achieves optimal balance between processability and performance characteristics such as wear resistance and wet performance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite materials by combining copolymer rubber obtained by copolymerizing 1,3-butadiene and styrene with other diene rubber in specific ratios (not less than 50 wt.% copolymer rubber and not greater than 50 wt.% other diene rubber). This composite approach allows the material to exhibit both good processability and enhanced wear resistance and wet performance.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves excellent processability and manufacturing of tires with enhanced wear resistance and wet performance, balancing energy efficiency and gripping force.

Implementation Method 1

a silane coupling agent represented by Formula (2) below... the silane coupling agent (C) is a silane coupling agent represented by Formula (2) below... which enhances the interaction between the rubber and silica

Methodology Applied
Scientific EffectSilane coupling: Chemical Bonding

Implementation Method 2

a CTAB (cetyltrimethylammonium bromide) adsorption specific surface area of from 160 to 300 m2/g... a CTAB adsorption specific surface area of the silica (B) is from 180 to 250 m2/g

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS11787923B2Rubber composition for tire and pneumatic tire
Publication Date: 2023.10.17 THE YOKOHAMA RUBBER CO LTD
  • US11787923B2 patent drawing
  • US11787923B2 patent drawing
  • US11787923B2 patent drawing

AI summary

A rubber composition of the present technology contains: diene rubber (A) containing a predetermined amount of specific conjugated diene rubber represented by a predetermined formula; silica having a CTAB adsorption specific surface area in a predetermined range; and a silane coupling agent represented by a predetermined formula.