Enclosed Nanochannels via Silica Nanoparticle Self-Assembly

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

There is a need for a simple and inexpensive method to fabricate enclosed nanochannel structures using nanoparticles, as existing methods for nanofluidic applications are not efficient or cost-effective.

Innovation Solution

The method involves depositing a photosensitive film stack over a substrate, forming a pattern using interferometric lithography, and then depositing silica nanoparticles to create enclosed nanochannels, with the pattern being removed while retaining the structure formed by the nanoparticles, allowing for the formation of multilayer silica nanochannel structures with varying spatial periods and aspect ratios.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If thermal oxidation or nanoimprint is used to fabricate nanochannels, then nanochannel structures can be formed, but the fabrication process becomes complex and expensive

Engineering Contradiction:
Improvenanochannel structure formationVSAvoidfabrication process
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The fabrication process is divided into distinct segments: forming a sacrificial pattern layer with periodic structures, depositing silica nanoparticles as a separate layer, and then selectively removing the pattern layer. This segmentation allows each step to be optimized independently and simplifies the overall process compared to thermal oxidation or nanoimprint methods

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

A sacrificial pattern layer is introduced as an intermediary element that guides nanoparticle assembly during fabrication but is subsequently removed. This intermediary enables precise nanochannel formation without requiring complex direct patterning techniques, reducing overall device complexity

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If conventional lithography and nanoparticle assembly methods are used, then nanochannel structures can be formed, but the fabrication cost increases

Engineering Contradiction:
Improvenanochannel structure formationVSAvoidfabrication cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

Silica nanoparticles self-assemble into ordered arrays guided by the periodic pattern structures, eliminating the need for expensive top-down lithographic patterning of the nanochannels themselves. The system uses its own components (pattern structures and nanoparticles) to automatically form the desired structure through self-organization

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The sacrificial pattern structures serve as temporary, low-cost guides that are removed after serving their purpose. These disposable pattern elements enable precise nanochannel formation without requiring expensive permanent tooling or complex equipment

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If enclosed nanochannels are formed using existing methods, then nanofluidic applications can be achieved, but the methods are not efficient

Engineering Contradiction:
Improvenanofluidic application performanceVSAvoidfabrication efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The periodic pattern structures are formed in advance before nanoparticle deposition, creating a pre-configured template that guides subsequent self-assembly. This preliminary action ensures high reliability of the final structure while improving efficiency by eliminating the need for complex real-time control during nanoparticle placement

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the fabrication of scalable, cost-effective nanochannel structures suitable for applications in photonics, sensory, biological separation, and nanofluidics, with the ability to selectively separate fluid components and control spatial and size parameters of the nanochannels.

Implementation Method 1

forming a pattern on the film stack using interferometric lithography

Methodology Applied
Scientific EffectInterference: Interference

Implementation Method 2

depositing a plurality of silica nanoparticles to form a structure over the pattern

Methodology Applied
Scientific EffectSelf-Assembly: Self-Assembly

Data Source

PatentUS8404123B2Fabrication of enclosed nanochannels using silica nanoparticles
Publication Date: 2013.03.26 STC UNM
  • US8404123B2 patent drawing
  • US8404123B2 patent drawing
  • US8404123B2 patent drawing

AI summary

In accordance with the invention, there is a method of forming a nanochannel including depositing a photosensitive film stack over a substrate and forming a pattern on the film stack using interferometric lithography. The method can further include depositing a plurality of silica nanoparticles to form a structure over the pattern and removing the pattern while retaining the structure formed by the plurality of silica nanoparticles, wherein the structure comprises an enclosed nanochannel.