Silica Sol Production Using Linked Core Particles for CMP

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Solution Overview

Problem

Existing methods for producing silica sols do not effectively increase the ratio of heteromorphized silica particles, which are necessary for improving polishing rates in chemical mechanical polishing processes.

Innovation Solution

A method involving the preparation of a first liquid with silica core particles having an average diameter of 20 nm or less, followed by holding this liquid for 72 hours or longer to form linked silica core particles, which are then further processed to enhance the heteromorphization of silica particles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If existing methods for producing silica sol are used, then silica particles can be obtained, but the ratio of heteromorphized silica particles is insufficient

Engineering Contradiction:
Improveratio of heteromorphized silica particlesVSAvoidpolishing rate
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent changes key parameters including using silica core particles with average diameter of 20 nm or less (size parameter), holding the first liquid for 72 hours or longer (time parameter), and controlling the composition ratios of alkoxysilane, water, and organic solvent (concentration parameters) to achieve high ratio of heteromorphized silica particles

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent performs preliminary formation of silica core particles with controlled size (20 nm or less) before the main heteromorphization process. This preliminary action of creating small uniform cores enables subsequent efficient heteromorphization during the holding period, leading to higher polishing rates

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method significantly increases the ratio of heteromorphized silica particles, leading to improved polishing rates and reduced surface roughness in CMP processes.

Implementation Method 1

preparing a first liquid including silica core particles having an average value of longest diameters of primary particles of 20 nm or less, and preparing a second liquid including linked silica core particles by holding the first liquid for 72 hours or longer

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

holding the first liquid for 72 hours or longer to form linked silica core particles

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentUS20250304451A1Method for producing silica sol and silica sol
Publication Date: 2025.10.02 FUJIMI INCORPORATED
  • US20250304451A1 patent drawing

AI summary

Provided is a method for producing a silica sol capable of increasing the ratio of heteromorphized silica particles. A method for producing a silica sol according to an aspect of the present disclosure includes a step of preparing a first liquid including silica core particles having an average value of longest diameters of primary particles of 20 nm or less, and a step of preparing a second liquid including linked silica core particles by holding the first liquid for 72 hours or longer.