Silicate-Based Stainless Steel Coating for High-Temperature Yellowing

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Solution Overview

Problem

Stainless steel surfaces coated with traditional chrome-based coatings can yellow and crack when exposed to high temperatures, and glass-based coatings can roughen and whiten due to moisture exposure, while existing coating methods struggle to provide uniform coverage on curved surfaces.

Innovation Solution

A composition comprising sodium silicate, lithium silicate, polysiloxane, ethanol, and a residual solvent, applied as a spray coating, which forms a durable, heat-resistant, and moisture-resistant layer that prevents yellowing and whitening, and ensures uniform coverage on stainless steel surfaces.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a chrome passive film coating is applied to prevent moisture permeability and yellowing, then the stainless steel surface is protected from yellowing at room temperature, but the coating becomes denaturalized and cracks when exposed to high temperatures of 250°C or more

Engineering Contradiction:
Improveprotection from yellowingVSAvoidcoating integrity
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent changes the chemical composition parameters of the coating by replacing traditional chrome-based materials with a silicate-based composition containing specific ratios of sodium silicate, lithium silicate, and other components. This compositional parameter change enables the coating to maintain both protective properties and thermal stability up to 400°C or higher, resolving the contradiction between room temperature protection and high temperature integrity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite coating formulation combining multiple silicate compounds (sodium silicate, lithium silicate), metal oxides, and organic additives in specific proportions. This composite material approach creates a coating that exhibits both the moisture barrier properties needed for yellowing prevention and the thermal stability required to avoid cracking at high temperatures.

Inventive Principle:
Principle #40Composite materials

2Reliability

If a glass component is added to the stainless coating to remove contaminants and prevent yellowing, then the coating gains cleaning ability and yellowing resistance, but the coating roughens and whitens when exposed to water for a long time

Engineering Contradiction:
Improvecontaminant removal and yellowing preventionVSAvoidsurface stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent modifies the glass component parameters by using specific types and ratios of silicates (sodium silicate 5-20 wt%, lithium silicate 3-20 wt%) instead of traditional glass particles. This parameter change maintains the contaminant removal and yellowing prevention capabilities while significantly improving water resistance and preventing the roughening and whitening that occurs with conventional glass-based coatings.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific organic additives and metal oxides as intermediary components that act between the silicate base and the environment (water, contaminants). These intermediary substances enhance the overall performance by improving water resistance and surface stability while maintaining the contaminant removal and yellowing prevention properties of the silicate system.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If dip coating or roll coating is used to apply the stainless coating, then the coating process is simple and efficient, but curved surfaces cannot be uniformly coated

Engineering Contradiction:
Improvecoating process simplicityVSAvoidcoating uniformity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent changes the rheological parameters of the coating composition by adjusting viscosity, particle size distribution, and solvent content. These parameter modifications enable the coating to flow and level properly during spray application, ensuring uniform coverage on curved surfaces while maintaining process efficiency.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent is specifically designed for spray coating application, utilizing pneumatic spray systems to deliver the coating composition. The formulation parameters are optimized for spray application characteristics, enabling uniform deposition on complex geometries and curved surfaces, which neither dip coating nor roll coating can achieve uniformly.

Inventive Principle:
Principle #29Pneumatics and hydraulics

4Manufacturing precision

If the coating is sprayed onto the stainless surface to achieve uniform coverage on curved surfaces, then coating uniformity is improved, but the application may not be smooth depending on particle size

Engineering Contradiction:
Improvecoating uniformityVSAvoidapplication smoothness
Core Design Contradiction:
Manufacturing precisionVSEase of operation

Solution Approach 1:

The patent optimizes the particle size parameters of the silicate components and other solid particles in the coating formulation. By controlling particle size distribution within specific ranges and using appropriate particle morphology, the coating achieves both uniform coverage on curved surfaces and smooth application characteristics during spray coating, resolving the contradiction between coating uniformity and application smoothness.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively prevents contaminants from adhering to stainless steel surfaces, maintains a shiny appearance, and enhances durability and moisture resistance, allowing for easy cleaning and maintaining a clean aesthetic even at high temperatures, while ensuring a smooth and uniform coating on curved surfaces.

Implementation Method 1

a composition comprising sodium silicate, lithium silicate, polysiloxane, ethanol, and a residual solvent

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Implementation Method 2

oxygen may not permeate the stainless coating

Methodology Applied
Scientific EffectPermeation: Permeation

Implementation Method 3

prevents contaminants from adhering to stainless steel surfaces

Methodology Applied
Scientific EffectSurface Tension: Surface Tension

Implementation Method 4

contaminants incurred during cooking may adhere to a stainless steel surface

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 5

A stainless or protective coating including a chrome passive film may be formed on the stainless steel surface to prevent moisture permeability

Methodology Applied
Scientific EffectPassive Film Formation:

Implementation Method 6

maintains a shiny appearance, and enhances durability and moisture resistance

Methodology Applied
Scientific EffectHydrophobe: Hydrophobe

Data Source

PatentUS11767434B2Composition for a stainless coating, stainless member including the stainless coating, and method of manufacturing same
Publication Date: 2023.09.26 LG ELECTRONICS INC
  • US11767434B2 patent drawing
  • US11767434B2 patent drawing
  • US11767434B2 patent drawing

AI summary

A composition for a stainless coating according to the present disclosure includes a sodium silicate, a lithium silicate, a polysiloxane, ethanol, and a residual solvent. The composition may be uniformly and smoothly coated on a curved, stainless steel surface, cleaning may be easier, and yellowing may be reduced or prevented.