In Situ Pre-lithiation for Silicon Anode Batteries

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Solution Overview

Problem

Lithium-ion batteries with silicon anodes experience significant lithium-ion loss during the first charge/discharge cycle, leading to reduced efficiency and capacity, which existing technologies fail to adequately address.

Innovation Solution

The method involves applying a voltage across the anode and cathode during a formation charging process to transfer lithium ions from the cathode to the anode, utilizing a cathode with a matrix of particles having core and shell regions to increase lithium capacity and compensate for ion loss, thereby performing in situ pre-lithiation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If a silicon anode is used to increase battery capacity, then the energy storage capability is improved, but significant lithium-ion loss occurs during the first charge/discharge cycle

Engineering Contradiction:
Improvelithium-ion capacityVSAvoidlithium-ion loss
Core Design Contradiction:
Quantity of substanceVSLoss of substance

Solution Approach 1:

The patent applies preliminary action by performing pre-lithiation of the silicon anode before the battery enters normal operation. Lithium ions are intentionally added to the anode during manufacturing or initial cycles to compensate for the lithium-ion loss that will occur during the first charge/discharge cycle. This preliminary compensation ensures that sufficient lithium ions remain available for subsequent operational cycles, resolving the contradiction between using silicon anodes for high capacity and suffering from initial lithium-ion loss.

Inventive Principle:
Principle #10Preliminary action

2Productivity

If pre-lithiation is performed to compensate for lithium-ion loss, then battery efficiency is improved, but additional process steps are required

Engineering Contradiction:
Improvebattery efficiencyVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent employs self-service by enabling the battery system to perform its own pre-lithiation through integrated design elements. The cathode structure is specifically engineered with excess lithium content and controlled morphology to automatically provide the necessary lithium ions to the silicon anode during initial cycles without requiring external intervention or separate pre-lithiation equipment. This self-service approach improves battery efficiency while minimizing additional process complexity by incorporating the pre-lithiation function into the battery's inherent structure.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances lithium-ion retention, improves battery efficiency, and extends the battery's lifespan by preventing lithium-ion loss and solid-electrolyte interphase formation during subsequent charge/discharge cycles.

Implementation Method 1

transferring lithium ions from the cathode to the anode to perform in situ pre-lithiation

Methodology Applied
Scientific EffectIon transfer: Ion Repulsion/Attraction

Data Source

PatentUS10811732B1Pre-lithiation for batteries having si-anodes
Publication Date: 2020.10.20 GOOGLE LLC
  • US10811732B1 patent drawing
  • US10811732B1 patent drawing
  • US10811732B1 patent drawing

AI summary

The disclosure relates to pre-lithiation for batteries having silicon anodes. One example embodiment is a method. The method includes applying a voltage across an anode and a cathode of a battery during a formation charging process. The method also includes transferring lithium ions from the cathode to the anode to perform in situ pre-lithiation. A ratio of a capacity of the anode to a capacity of the cathode is less than 1.0.