Silicon-Modified Capacitor Electrode and Dielectric Interface

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Solution Overview

Problem

Existing capacitor technologies face challenges in increasing capacity density and withstand voltage simultaneously, as thicker hafnium oxide dielectric layers decrease field strength and lead to increased leakage currents.

Innovation Solution

A capacitor design featuring a dielectric layer with a silicon concentration distribution that includes a convex portion intersecting the interface between the electrodes, using materials like hafnium oxide or zirconium oxide, and introducing silicon into the electrode before forming the dielectric layer to compensate for defects and enhance withstand voltage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If a thicker hafnium oxide dielectric layer is used to increase capacity, then the dielectric constant increases, but the field strength decreases and leakage current increases

Engineering Contradiction:
ImprovecapacityVSAvoidleakage current
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent applies local quality by creating a non-uniform silicon concentration distribution within the dielectric layer. A convex portion of silicon concentration is formed at the interface between the electrode and dielectric layer, while other regions maintain different silicon concentrations. This localized variation in composition allows the dielectric layer to simultaneously achieve high capacity (through overall thickness and dielectric constant) and low leakage current (through the silicon-rich interface region that suppresses defect formation and current paths).

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent employs composite materials by combining hafnium oxide with silicon to form a composite dielectric layer. The dielectric layer contains both hafnium oxide providing high dielectric constant and silicon providing defect compensation and leakage suppression. The convex portion of silicon concentration at the interface creates a composite structure that integrates the benefits of both materials: high capacity from hafnium oxide and improved reliability from silicon.

Inventive Principle:
Principle #40Composite materials

2Reliability

If silicon is introduced into the electrode before forming the dielectric layer, then defects in the dielectric layer are compensated, but the manufacturing process becomes more complex

Engineering Contradiction:
Improvewithstand voltageVSAvoidmanufacturing process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by introducing silicon into the electrode surface before forming the dielectric layer. This pre-introduction of silicon creates a silicon-containing electrode structure that will subsequently form a silicon-rich interface region when the dielectric layer is deposited. This preliminary silicon introduction compensates for defects in the dielectric layer during the deposition process itself, improving withstand voltage without requiring separate defect compensation steps.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent merges multiple functions into a single manufacturing step. By introducing silicon into the electrode before dielectric layer formation, the process combines electrode preparation and defect compensation into one operation. The silicon introduction step simultaneously prepares the electrode surface for dielectric deposition and establishes the silicon concentration distribution that will compensate for defects, reducing the need for additional separate process steps.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design effectively increases both the capacity and withstand voltage of the capacitor by distributing silicon to compensate for defects in the dielectric layer, suppressing current path formation and improving voltage characteristics.

Implementation Method 1

the first portion and the second portion each contain silicon. A concentration distribution of the silicon along a thickness direction of the first portion and the second portion includes a convex portion intersecting the interface

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS10923560B2Capacitor including electrode and dielectric layer each containing silicon, and method for manufacturing capacitor
Publication Date: 2021.02.16 PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
  • US10923560B2 patent drawing
  • US10923560B2 patent drawing
  • US10923560B2 patent drawing

AI summary

A capacitor includes a first electrode; a second electrode facing the first electrode; and a dielectric layer which is disposed between the first electrode and the second electrode and which is in contact with the first electrode. The first electrode includes a first portion including an interface between the first electrode and the dielectric layer, the dielectric layer includes a second portion including the interface, and the first portion and the second portion each contain silicon. A concentration distribution of the silicon along a thickness direction of the first portion and the second portion includes a convex portion intersecting the interface.