Silicon-Carbon Anode Material for Higher Initial Efficiency

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Solution Overview

Problem

Current silicon anode materials for lithium ion batteries have low initial efficiency and complex, costly lithium supplementation methods, limiting their application in full cell designs.

Innovation Solution

An anode material comprising an active material, carbon material, and dopant element, where the dopant induces Lewis acid sites, enhancing bonding and graphitization, thereby improving conductivity and stability, and a preparation method involving heat treatment and carbon coating to increase the degree of graphitization and reduce costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If silicon anode material is used to increase capacity, then energy density is improved, but initial efficiency deteriorates

Engineering Contradiction:
Improveenergy densityVSAvoidinitial efficiency
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent applies preliminary action by pre-lithiating the silicon anode material before battery assembly. Lithium powder is mixed with silicon material and subjected to ball milling treatment, introducing lithium into the silicon structure in advance. This preliminary lithium supplementation ensures that when the battery operates for the first time, there is sufficient lithium to form the solid electrolyte interface film and accommodate silicon expansion, thereby improving initial efficiency while maintaining high energy density

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent employs composite materials by creating a composite structure consisting of silicon particles, lithium powder, and carbon coating. The silicon provides high capacity, lithium supplements initial efficiency, and carbon coating stabilizes the structure. This composite approach allows the anode to achieve both high energy density from silicon and improved initial efficiency from lithium, resolving the contradiction between these two parameters

Inventive Principle:
Principle #40Composite materials

2Reliability

If lithium supplementation techniques are applied to improve initial efficiency, then initial efficiency is improved, but device complexity increases

Engineering Contradiction:
Improveinitial efficiencyVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the lithium supplementation process with the existing anode material preparation process. Instead of using separate complex supplementation techniques after battery assembly, the patent combines lithium powder mixing and ball milling treatment into the standard anode material fabrication workflow. This integration allows initial efficiency improvement to be achieved during normal production without requiring additional complex equipment or process steps

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent applies self-service by allowing the anode material to self-regulate lithium distribution through the ball milling process. The mechanical energy from ball milling automatically distributes lithium powder throughout the silicon material and creates appropriate contact interfaces, eliminating the need for external intervention or complex control systems to manage lithium supplementation

Inventive Principle:
Principle #25Self-service

3Reliability

If lithium supplementation techniques are applied to improve initial efficiency, then initial efficiency is improved, but manufacturing cost increases

Engineering Contradiction:
Improveinitial efficiencyVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent uses cheap short-living objects by employing lithium powder, a low-cost material, instead of expensive lithium metal foils or complex lithium supplementation devices. The lithium powder is mixed with silicon and processed through conventional ball milling, using readily available equipment. This approach achieves initial efficiency improvement at minimal material and equipment cost, making the process economically viable for mass production

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The anode material exhibits improved initial efficiency, cycling stability, and reduced expansion rate, facilitating better performance and longer cycle life in lithium ion batteries.

Implementation Method 1

the dopant element is capable of inducing the carbon material to produce a Lewis acid site, and at least a portion of the active material is bound to the carbon material though the Lewis acid site

Methodology Applied
Scientific EffectLewis acid site formation: Chemical Bonding

Implementation Method 2

a primary heat treatment at 800° C. to 980° C. to obtain an aggregate

Methodology Applied
Scientific EffectGraphitization: Heat Treatment

Implementation Method 3

undergoing the precursor a primary heat treatment at 800° C. to 980° C. to obtain an aggregate

Methodology Applied
Scientific EffectThermal energy conversion: Heating

Implementation Method 4

a G band is observed at 1530 cm−1 to 1630 cm−1, and a D band is observed at 1280 cm−1 to 1380 cm−1, and a ratio ID/IG of between peak intensity ID of the D band and peak intensity IG of the G band is 1 to 2.5

Methodology Applied
Scientific EffectRaman scattering: Scattering

Data Source

PatentUS20230378474A1Anode material and preparation method thereof, lithium ion battery
Publication Date: 2023.11.23 BTR NEW MATERIAL GRP CO LTD
  • US20230378474A1 patent drawing

AI summary

Providing an anode material and a preparation method thereof, lithium ion battery. The anode material includes an aggregate, the aggregate includes an active material, a carbon material, and a dopant element, where the carbon material is shown in a Raman spectrum obtained by Raman spectroscopy using a measurement light source having a wavelength of 532 nm that a G band is observed at 1530 cm−1 to 1630 cm−1, and a D band is observed at 1280 cm−1 to 1380 cm−1, and a ratio ID/IG of between peak intensity ID of the D band and peak intensity IG of the G band is 1 to 2.5. The anode material of the present application may significantly enhance the initial efficiency of composite material, and cycle performance and stability are also greatly improved.