Silicon-Containing Composition for Surface Retention

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Solution Overview

Problem

Silicon-containing compounds used to treat article surfaces often have poor retention, leading to defective products and increased production costs due to the need for repeated treatments, as they fail to maintain improved surface properties such as reduced surface tension and increased hydrophobicity effectively.

Innovation Solution

A composition comprising a first silicon-containing compound with a polyvalent transition metal and a second silicon-containing compound formed from specific reactants, including a perfluorohydrocarbyl group, which is applied to form a layer on articles to enhance surface retention and durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional silicon-containing compounds are used to treat article surfaces, then surface properties such as reduced surface tension and increased hydrophobicity are achieved, but retention on the surface is poor leading to defective products and increased production costs

Engineering Contradiction:
Improvesurface retentionVSAvoidproduction costs
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent applies composite materials by combining silicon-containing compounds with specific molecular structures (including perfluorohydrocarbyl groups and siloxane backbones) to create a hybrid material system. This composite approach leverages the hydrophobic properties of fluorinated groups and the adhesive characteristics of silicon-oxygen-silicon bonds, achieving both improved surface retention and maintained surface properties while reducing the need for repeated treatments

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent implements parameter changes by modifying the molecular structure of silicon-containing compounds through varying the perfluorohydrocarbyl group chain lengths (R4 groups with different carbon chain lengths), siloxane backbone configurations, and crosslinking densities. These structural parameter adjustments optimize the balance between surface retention, hydrophobicity, and durability, allowing the coating to maintain effectiveness over extended periods

Inventive Principle:
Principle #35Parameter changes

2Duration of action of stationary object

If conventional silicon-containing compounds are applied to article surfaces, then initial surface properties are improved, but durability over time is insufficient requiring repeated treatments

Engineering Contradiction:
ImprovedurabilityVSAvoidtime for repeated treatments
Core Design Contradiction:
Duration of action of stationary objectVSLoss of time

Solution Approach 1:

The patent applies preliminary action by incorporating pre-formed silicon-containing compounds with specific molecular architectures (including perfluorohydrocarbyl groups and siloxane structures) into the coating formulation before application. These pre-engineered molecules are designed to self-assemble and form durable networks upon contact with the article surface, ensuring long-lasting performance from the initial treatment without requiring subsequent maintenance applications

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent implements continuity of useful action through the formation of a persistent silicon-oxygen-silicon crosslinked network that maintains surface properties continuously over time. The molecular structure design ensures that the hydrophobic perfluorohydrocarbyl groups remain oriented toward the surface while the siloxane backbone provides continuous adhesion, creating a self-sustaining protective layer that resists degradation and maintains functionality without interruption

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The described composition significantly improves surface retention and durability, reducing the need for repeated treatments and lowering production costs by maintaining enhanced surface properties like reduced surface tension and increased hydrophobicity.

Implementation Method 1

modifying the surface properties, such as reducing the surface(s) tension and increasing the hydrophobicity

Methodology Applied
Scientific EffectSurface tension reduction: Surfactant

Implementation Method 2

increasing the hydrophobicity, of such articles

Methodology Applied
Scientific EffectHydrophobicity: Hydrophobe

Data Source

PatentUS9725619B2Composition including silicon-containing compounds
Publication Date: 2017.08.08 ACULON INC
  • US9725619B2 patent drawing
  • US9725619B2 patent drawing
  • US9725619B2 patent drawing

AI summary

Compositions including first and second silicon-containing compounds are described. The first silicon-containing compound includes a polyvalent transition metal having bonded thereto a hydrocarbyloxy group(s) and/or a (di-hydrocarbyl)(perfluoro/fluorinated-hydrocarbyl)silyloxy group(s), which is represented by Formula (I). The second silicon-containing compound includes a reaction product of a first reactant represented by Formula (II-A), which includes hyrdrocarbylsilyloxy groups, and a second reactant represented by Formula (II-B), which includes a perfluorohydrocarbyloxy group(s). The present invention also relates to, articles that include one or more layers formed from such compositions, methods of treating articles by applying thereover such compositions, and the second silicon-containing compound.