Silicon Compound Hard Coating Film Self-Healing Diselenide

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Solution Overview

Problem

Conventional hard coating films for display devices suffer from inadequate anti-scratch characteristics and strength, particularly when thickness is reduced for slim, lightweight designs, and compatibility issues with polyimide resins lead to degraded light transmissivity.

Innovation Solution

A silicon compound with adjacent siloxane moieties linked via a diselenide group is used, providing a self-healing mechanism that improves hardness and anti-scratch properties by re-forming the diselenide group under light irradiation, even after dissociation due to external stress, and is incorporated into a hard coating film or prism sheet.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Weight of moving object

If the thickness of the hard coating film is reduced to achieve slim and lightweight display devices, then the weight and size of the device are reduced, but the anti-scratch characteristics and strength of the hard coating film deteriorate

Engineering Contradiction:
Improveweight of display deviceVSAvoidanti-scratch characteristics
Core Design Contradiction:
Weight of moving objectVSStrength

Solution Approach 1:

The patent changes the chemical composition parameters of the hard coating film by incorporating specific resin combinations (polymer resin with epoxy group, polyimide resin, and acrylic resin) and controlling their weight ratios. This allows achieving sufficient hardness and anti-scratch properties even at reduced film thickness, resolving the contradiction between thinness and strength

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite material system combining multiple resin types (polymer resin containing epoxy group, polyimide resin, and acrylic resin) with complementary properties. The polymer resin provides adhesion and flexibility, polyimide resin contributes to hardness, and acrylic resin enhances scratch resistance, creating a synergistic effect that maintains strength at reduced thickness

Inventive Principle:
Principle #40Composite materials

2Strength

If polyimide resin is added to improve hardness, then the hardness of the hard coating film is improved, but compatibility with acrylate-based resin deteriorates and light transmissivity is degraded

Engineering Contradiction:
ImprovehardnessVSAvoidcompatibility and light transmissivity
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies local quality by assigning specific functions to different resin components: the polymer resin with epoxy group provides adhesion and compatibility, the polyimide resin contributes hardness in specific proportions, and the acrylic resin enhances scratch resistance. This localized functional assignment allows optimizing each property without compromising overall compatibility and light transmissivity

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent precisely controls the weight ratios of different resins to achieve optimal balance. By adjusting the content of polyimide resin relative to other components, the patent achieves sufficient hardness while maintaining compatibility with acrylate-based resin and preserving light transmissivity, resolving the contradiction between hardness and optical properties

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The silicon compound enhances the durability and hardness of the hard coating film, preventing surface damage and maintaining optical clarity, enabling the creation of lightweight, thin display devices without the need for cover glass.

Implementation Method 1

providing a self-healing mechanism that improves hardness and anti-scratch properties by re-forming the diselenide group under light irradiation, even after dissociation due to external stress

Methodology Applied
Scientific EffectPhotochemical reaction: Photopolymerisation

Data Source

PatentUS10698241B2Silicon compound and hard coating film and display device including the same
Publication Date: 2020.06.30 LG DISPLAY CO LTD
  • US10698241B2 patent drawing
  • US10698241B2 patent drawing
  • US10698241B2 patent drawing

AI summary

A liquid crystal display device includes a liquid crystal panel; and a backlight unit disposed at one side of the liquid crystal panel. The backlight unit includes a prism sheet, which comprises a base and a plurality of prism patterns arranged on the base and a binder and a silicon compound having adjacent siloxane moieties linked via a diselenide group, and a light source disposed at a lower portion of the prism sheet. In the liquid crystal display device, the prism sheet is disposed between the light source and the liquid crystal panel.