Silicon-Containing Compound for OLED Emission Efficiency

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Solution Overview

Problem

Current organic electroluminescence devices face challenges in reducing driving voltage, enhancing emission efficiency, and extending lifespan, particularly in the development of stable materials that can effectively address these requirements.

Innovation Solution

Incorporating a silicon-containing compound represented by a specific formula into the organic electroluminescence device structure, including it in the hole transport region, emission layer, or electron transport region, which improves emission efficiency and stability, and is suitable for thermally activated delayed fluorescence applications.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If traditional organic materials are used in the emission layer, then the device structure is simple, but the emission efficiency and lifespan are insufficient

Engineering Contradiction:
Improveemission efficiencyVSAvoidlifespan
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The patent introduces a silicon-containing compound with specific molecular structure parameters (Formula 1) that changes the physical and chemical properties of the emission layer. The silicon atom with its specific coordination geometry and bond angles modifies the HOMO-LUMO energy levels and charge transport characteristics, thereby improving both emission efficiency and device lifespan simultaneously.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite material system where the silicon-containing compound (Formula 1) is integrated into the organic emission layer. This composite approach combines the benefits of traditional organic materials with the superior charge transport and stability properties of silicon-based compounds, achieving enhanced emission efficiency and extended operational lifetime.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If materials that increase emission efficiency are used, then light output improves, but driving voltage increases

Engineering Contradiction:
Improvelight emitting efficiencyVSAvoiddriving voltage
Core Design Contradiction:
Illumination intensityVSPower

Solution Approach 1:

The silicon-containing compound modifies the energy level parameters of the emission layer, creating optimal HOMO-LUMO gaps that facilitate efficient electron-hole recombination at lower energy inputs. The specific structural parameters of Formula 1 enable better charge carrier mobility, reducing the voltage required to achieve high light emitting efficiency.

Inventive Principle:
Principle #35Parameter changes

3Duration of action of stationary object

If stable materials are used to extend lifespan, then device durability improves, but emission efficiency decreases

Engineering Contradiction:
ImprovelifespanVSAvoidemission efficiency
Core Design Contradiction:
Duration of action of stationary objectVSProductivity

Solution Approach 1:

The patent creates a composite emission layer that combines the stability of silicon-containing compounds with the high emission efficiency characteristics of organic luminescent materials. The silicon-based host material provides structural stability and long operational lifetime, while the integrated luminescent centers maintain high emission efficiency, resolving the trade-off between durability and performance.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The silicon-containing compound enhances emission efficiency and extends the lifespan of organic electroluminescence devices, achieving higher maximum light emitting efficiency and longer brightness half-life compared to traditional materials, while maintaining low driving voltage.

Implementation Method 1

which improves emission efficiency and stability, and is suitable for thermally activated delayed fluorescence applications

Methodology Applied
Scientific EffectThermally activated delayed fluorescence: Phosphorescence

Data Source

PatentUS11283031B2Organic electroluminescence device and silicon-containing compound for organic electroluminescence device
Publication Date: 2022.03.22 SAMSUNG DISPLAY CO LTD
  • US11283031B2 patent drawing
  • US11283031B2 patent drawing
  • US11283031B2 patent drawing

AI summary

A silicon-containing compound represented by Formula 1 and an organic electroluminescence device including the same in at least one of a plurality of organic layers of the device are provided.