Large Diameter Silicon Single Crystal Growth Control

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Solution Overview

Problem

Current methods fail to produce silicon single crystals with favorable macroscopic and microscopic resistivity distribution, particularly for large diameter (111) silicon wafers, which are essential for cutting-edge devices using next-generation channel materials.

Innovation Solution

The Czochralski method is employed while applying a magnetic field to control the growth conditions, setting the diameter and growth axis orientation to promote (111) lateral growth, ensuring a ratio of 1096/D−(0.134×M+80×R)/D>0.7, where D is the crystal diameter, M is the magnetic field strength, and R is the rotation rate, resulting in a silicon single crystal with 70% or more of the surface area as lateral growth.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a silicon single crystal is grown by conventional Czochralski method without magnetic field control, then the growth process is simple, but the macroscopic radial distribution of resistivity is unfavorable and microscopic variation is high

Engineering Contradiction:
Improveresistivity distribution uniformityVSAvoidgrowth control complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies a magnetic field during the Czochralski growth process to control melt convection and solid-liquid interface morphology. By changing the physical parameter (magnetic field application), the patent achieves favorable macroscopic radial distribution of resistivity and reduced microscopic variation, resolving the contradiction between manufacturing precision and process simplicity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent establishes a quantitative relationship between growth parameters (diameter D, magnetic field strength M, rotation rate R) and growth quality through the formula 1096/D−(0.134×M+80×R)/D>0.7. This feedback mechanism allows precise control of lateral growth to achieve 70% or more of the crystal surface as lateral growth, improving resistivity distribution uniformity

Inventive Principle:
Principle #23Feedback

2Area of stationary object

If the crystal diameter is increased to 300 mm or more for large diameter wafers, then the wafer area increases for better device integration, but the control of lateral growth and resistivity distribution becomes more difficult

Engineering Contradiction:
Improvewafer areaVSAvoidlateral growth control
Core Design Contradiction:
Area of stationary objectVSManufacturing precision

Solution Approach 1:

The patent specifically addresses large diameter crystal growth (D≥300 mm) by incorporating the diameter parameter into the control formula 1096/D−(0.134×M+80×R)/D>0.7. The magnetic field strength and rotation rate are adjusted as functions of diameter to maintain optimal lateral growth control across different scale sizes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces magnetic field control as an additional control dimension to manage the complexity of large diameter crystal growth. By adding magnetic field strength M as a controllable parameter, the system gains an extra degree of freedom to control lateral growth and resistivity distribution in large diameter wafers

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Manufacturing precision

If magnetic field strength is increased to control lateral growth, then the resistivity distribution improves, but the energy consumption and equipment complexity increase

Engineering Contradiction:
Improveresistivity distributionVSAvoidmagnetic field energy consumption
Core Design Contradiction:
Manufacturing precisionVSUse of energy by moving object

Solution Approach 1:

The patent provides a quantitative formula 1096/D−(0.134×M+80×R)/D>0.7 that defines the optimal magnetic field strength M as a function of crystal diameter and rotation rate. This allows achieving favorable resistivity distribution with minimized magnetic field strength, thereby reducing energy consumption while maintaining manufacturing precision

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of large diameter silicon single crystals with improved macroscopic radial distribution of resistivity and reduced microscopic variation, making the (111) silicon wafer suitable for high-yield miniaturization techniques and as a substrate for next-generation channel materials.

Implementation Method 1

pulling a silicon single crystal by Czochralski method while a magnetic field is applied to a raw material melt

Methodology Applied
Scientific EffectMagnetic field: Magnetic Field

Implementation Method 2

applying a magnetic field to control the growth conditions

Methodology Applied
Scientific EffectMagnetohydrodynamic effect: Magnetohydrodynamic Effect

Implementation Method 3

production of a silicon single crystal by Czochralski method

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 4

growth of a silicon single crystal

Methodology Applied
Scientific EffectSolidification: Freezing

Data Source

PatentUS11053606B2Method of producing silicon single crystal, and silicon single crystal wafer
Publication Date: 2021.07.06 SHIN ETSU HANDOTAI CO LTD
  • US11053606B2 patent drawing
  • US11053606B2 patent drawing
  • US11053606B2 patent drawing

AI summary

A method of producing a silicon single crystal, including pulling a silicon single crystal by Czochralski method while a magnetic field is applied to a raw material melt, including: setting a diameter on pulling the silicon single crystal to 300 mm or more, setting a growth axis direction of the silicon single crystal to <111>, and growing the silicon single crystal so as to satisfy a relation of 1096/D−(0.134×M+80×R)/D>0.7, wherein D [mm] is the diameter on pulling the silicon single crystal, M [Gauss] is a central magnetic field strength at a surface of the raw material melt, and R [rpm] is a rotation rate of the silicon single crystal. This makes it possible to produce a <111> crystal with favorable macroscopic RRG distribution and microscopic variation of resistivity.