Silicon Deposition for High Aspect Ratio Etch Profile Control

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Solution Overview

Problem

In semiconductor device formation, existing deposition methods fail to effectively prevent sidewall etching and bowing in high aspect ratio features, leading to poor etch profile control and increased complexity as feature sizes shrink.

Innovation Solution

A method involving the formation of a plasma in a processing chamber using silicon-containing and COS-containing gases to deposit a passivation layer comprising silicon, oxygen, and sulfur, which is highly resistant to etching and reduces sidewall etching, thereby maintaining a straight etch profile and preventing bowing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If existing deposition methods are used, then deposition can be formed, but sidewall etching and bowing occur in high aspect ratio features

Engineering Contradiction:
Improveetch profile controlVSAvoidsidewall etching resistance
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the deposition layer by using a novel gas mixture containing silicon-containing gas and COS-containing gas. This creates a deposition layer with specific silicon, oxygen, and sulfur composition that provides enhanced etch resistance while maintaining the desired deposition properties, thereby resolving the contradiction between etch profile control and sidewall etching resistance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite deposition layer containing multiple elements (silicon, oxygen, sulfur) deposited simultaneously from different gas sources. This composite material structure provides superior etch resistance compared to conventional single-element deposition layers, enabling effective prevention of sidewall etching in high aspect ratio features while maintaining good etch profile control

Inventive Principle:
Principle #40Composite materials

2Length of moving object

If feature sizes are reduced, then device scaling is achieved, but etch profile control deteriorates

Engineering Contradiction:
Improvefeature sizeVSAvoidetch profile control
Core Design Contradiction:
Length of moving objectVSManufacturing precision

Solution Approach 1:

By adjusting the chemical composition parameters of the deposition layer through controlled gas flow ratios of silicon-containing gas and COS-containing gas, the patent creates a deposition layer with optimized etch resistance properties. This enables maintaining precise etch profile control even as feature sizes are reduced for device scaling

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The deposition process is performed as a preliminary step before etching high aspect ratio features. This preliminary deposition of the specialized silicon-oxygen-sulfur layer prepares the sidewalls with enhanced etch resistance, ensuring that subsequent etching processes maintain excellent profile control regardless of the reduced feature dimensions

Inventive Principle:
Principle #10Preliminary action

3Reliability

If deposition layer is added for etch resistance, then sidewall protection is improved, but process complexity increases

Engineering Contradiction:
Improveetch resistanceVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the deposition of multiple elements (silicon, oxygen, sulfur) into a single deposition step by simultaneously flowing silicon-containing gas and COS-containing gas. This combined approach provides comprehensive etch resistance and sidewall protection without requiring multiple separate deposition steps, thereby avoiding increased process complexity while achieving superior etch resistance

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The deposited layer provides excellent etch resistance and improved step coverage, allowing for better control of etch profiles and preventing etch stop, while being easily removable without damaging features, thus enhancing the semiconductor device fabrication process.

Implementation Method 1

A plasma is formed from the silicon containing gas and the COS containing gas in the processing chamber, wherein the plasma provides the deposition over the substrate

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

A silicon containing gas is flowed into the processing chamber. A COS containing gas is flowed into the processing chamber. A plasma is formed from the silicon containing gas and the COS containing gas in the processing chamber

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Data Source

PatentUS10658194B2Silicon-based deposition for semiconductor processing
Publication Date: 2020.05.19 LAM RES CORP
  • US10658194B2 patent drawing
  • US10658194B2 patent drawing
  • US10658194B2 patent drawing

AI summary

A method for processing a substrate in a processing chamber, comprising forming a deposition over the substrate is provided. A silicon containing gas is flowed into the processing chamber. A COS containing gas is flowed into the processing chamber. A plasma is formed from the silicon containing gas and the COS containing gas in the processing chamber, wherein the plasma provides the deposition over the substrate.