Silicon Germanium OLED Compounds for Saturated Color Emission

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Solution Overview

Problem

Current organic light-emitting diode (OLED) technologies face challenges in achieving saturated color emission, particularly in red, green, and blue pixels, which is crucial for full-color displays, and existing materials may not efficiently utilize the properties of organic materials for enhanced performance.

Innovation Solution

A compound of Formula R1R2R3M-L-M′ is introduced, where M is Si or Ge, and L can be various bonds or groups, with specific substituents and structures, used in OLEDs to enhance the organic layer's performance, allowing for improved color emission and device efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional organic materials are used in OLEDs, then device fabrication and cost are advantageous, but achieving saturated color emission (particularly in red, green, and blue pixels) is difficult

Engineering Contradiction:
Improvecolor emission saturationVSAvoidmaterial performance optimization
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent modifies molecular parameters of organic compounds by introducing specific substituents (triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, dibenzofluorene, and their aza variants) at defined positions (R1, R2, R3) in the core structure. These parameter changes in molecular structure enable the material to achieve saturated color emission while maintaining OLED manufacturing advantages

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite organic compounds combining a core structure with specific substituent groups. The composite nature of these molecules (core + functional substituents) allows simultaneous achievement of saturated color emission and retention of organic material processing advantages

Inventive Principle:
Principle #40Composite materials

2Reliability

If existing organic materials are used, then flexibility and cost advantages are maintained, but device efficiency and color accuracy are insufficient

Engineering Contradiction:
Improvedevice efficiencyVSAvoidcolor accuracy
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies local quality modification by introducing specific functional groups (triphenylene, carbazole, dibenzothiophene, etc.) at specific positions (R1, R2, R3) of the molecular structure. This localized structural enhancement at key positions enables simultaneous improvement of device efficiency and color accuracy without compromising overall material performance

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

By changing molecular parameters through strategic substitution at defined positions, the patent optimizes both device efficiency and color accuracy. The parameter modifications in the organic compound structure enable saturated color emission while maintaining the flexibility and cost advantages of organic materials

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound enables the development of OLEDs with enhanced color accuracy and efficiency, potentially leading to better performance in display applications by optimizing the organic layer's properties and emission characteristics.

Implementation Method 1

OLEDs make use of thin organic films that emit light when voltage is applied across the device

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20240196733A1Organic electroluminescent materials and devices
Publication Date: 2024.06.13 UNIVERSAL DISPLAY CORP
  • US20240196733A1 patent drawing
  • US20240196733A1 patent drawing
  • US20240196733A1 patent drawing

AI summary

Provided are compounds of Formula R1R2R3M-L-M′; wherein M is Si or Ge; L is selected from the group consisting of a direct bond, or selected from the group consisting of O, S, Se, BR, BRR′, PR, CR, NR, C═O, C═S, C═NR, C═CRR′, CRR′, SO, SO2, SiRR′, GeRR′, and P(O)R; when L is a direct bond, M′ is SiR4R5R6 or GeR4R5R6; and when L is not a direct bond, M′ is SiR4R5R6, GeR4R5R6, or one or more hydrocarbon groups provided that at least one of the one or more hydrocarbon groups is a carbocyclic group. Also provided are formulations comprising these compounds. Further provided are organic light emitting devices (OLEDs) and related consumer products that utilize these compounds.