Photocurable Silicon Ink Composition for Low-k OLED Packaging

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Solution Overview

Problem

Existing organic light-emitting diode (OLED) package materials face issues with high dielectric constants and ink-jet printing blockages, which affect the stability and reliability of OLED devices.

Innovation Solution

An ink composition comprising a photocurable silicon-containing monomer component, an active diluent component, and a photoinitiator component, utilizing a fluorine-substituted silicon-containing monomer to form a free radical curing system that reduces dielectric constant and prevents ink hole blockage during printing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a fluorine-containing monomer is used to reduce dielectric constant, then dielectric constant is reduced, but ink hole blockage occurs during printing

Engineering Contradiction:
Improvedielectric constantVSAvoidink hole blockage
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the chemical structure parameters of the fluorine-containing monomer by introducing specific substituents (R1-R6 groups) and controlling the degree of fluorine substitution. This allows optimization of both dielectric constant and printing performance, resolving the contradiction between low dielectric constant and ink hole blockage prevention.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite material design by combining fluorine-containing monomers with specific substituents in a coordinated manner. The composite structure of the monomer molecule allows simultaneous achievement of low dielectric constant and resistance to ink hole blockage during printing processes.

Inventive Principle:
Principle #40Composite materials

2Length of moving object

If thin film package thickness is reduced to 1 micron, then device miniaturization is achieved, but planarization and gap filling functions are insufficient

Engineering Contradiction:
Improvepackage thicknessVSAvoidplanarization function
Core Design Contradiction:
Length of moving objectVSManufacturing precision

Solution Approach 1:

The patent designs the ink composition to perform multiple functions simultaneously: planarization, gap filling, and electrical insulation. By incorporating specific functional groups and adjusting the chemical composition, the thin film achieves multiple required functions despite the reduced thickness of 1 micron.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent adjusts the chemical composition parameters of the ink material to optimize its physical properties for thin film applications. By controlling molecular weight, functional group concentration, and other parameters, the material achieves adequate planarization and gap filling functions even at 1 micron thickness.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If ink-jet printing precision is increased for thin layers, then layer thickness control is improved, but printing process complexity increases

Engineering Contradiction:
Improvelayer thickness controlVSAvoidprinting process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent modifies the rheological parameters and chemical composition of the ink material to make it more suitable for ink-jet printing. By adjusting viscosity, surface tension, and other physical parameters, the printing process becomes less complex while maintaining precise layer thickness control at the 1 micron level.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink composition achieves a low dielectric constant, improves curing speed, and prevents ink hole blockage, enhancing the stability and reliability of OLED devices by forming a high-quality organic layer.

Implementation Method 1

an ink composition, which comprises: a photocurable silicon-containing monomer component, an active diluent component, and a photoinitiator component

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Implementation Method 2

utilizing a fluorine-substituted silicon-containing monomer to form a free radical curing system that reduces dielectric constant

Methodology Applied
Scientific EffectDielectric constant reduction: Dielectric Permittivity

Data Source

PatentUS20250388769A1Ink Composition, Package Structure and Semiconductor Device
Publication Date: 2025.12.25 HANGZHOU FIRST APPLIED MATERIAL CO LTD
  • US20250388769A1 patent drawing
  • US20250388769A1 patent drawing
  • US20250388769A1 patent drawing

AI summary

Provided are an ink composition, a package structure, and a semiconductor device. The ink composition includes: a photocurable silicon-containing monomer component, an active diluent component, and a photoinitiator component, wherein the photocurable silicon-containing monomer component comprises any one or more compounds having the following structural formula (I).