Silicon Oxide Anode Doping for Higher Initial Efficiency

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional lithium secondary batteries using silicon-based negative electrodes face issues with low energy density due to volume expansion during charging and discharging, and silicon oxide-based electrodes have poor initial coulombic efficiency and industrial usability due to irreversible phase formation and low electrical conductivity.

Innovation Solution

A negative electrode for lithium secondary batteries is developed, comprising silicon oxide, lithium, and sodium or potassium, with specific elemental content ratios to enhance initial coulombic efficiency and capacity, and a method involving pre-lithiation and doping processes to secure uniform current distribution and improved battery life characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If silicon-based negative electrode material is used to increase energy density, then theoretical capacity increases to 3580 mAh/g, but volume expansion reaches ~400% during repeated charging and discharging, causing poor battery life characteristics

Engineering Contradiction:
Improvetheoretical capacityVSAvoidbattery life characteristics
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent uses a composite material system consisting of silicon oxide particles embedded in a carbon matrix, rather than pure silicon. This composite structure combines the high capacity advantage of silicon with the structural stability and volume expansion resistance of carbon and silicon oxide, resolving the contradiction between high theoretical capacity and battery life reliability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical composition parameter from pure silicon to silicon oxide with specific ratios (SiO2 content of 1-50 wt%), which fundamentally alters the volume expansion behavior during lithiation. This parameter change reduces volume expansion from ~400% to manageable levels while maintaining high capacity, thus resolving the contradiction between capacity and life characteristics.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If silicon oxide-based negative electrode material is used to reduce volume expansion, then volume expansion rate decreases and life characteristics improve, but initial coulombic efficiency becomes poor due to irreversible phase formation

Engineering Contradiction:
Improvebattery life characteristicsVSAvoidinitial coulombic efficiency
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent optimizes the silicon oxide content parameter to a specific range (1-50 wt%, preferably 5-20 wt%) rather than using high silicon oxide content. This controlled parameter change balances the reduction of irreversible phase formation (improving initial efficiency) while maintaining sufficient structural stability (preserving life characteristics).

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a heterogeneous structure where silicon oxide is distributed as discrete particles within a carbon matrix, rather than uniform composition. This local quality differentiation allows silicon oxide to provide structural stability where needed while limiting its total amount to minimize irreversible reactions, thus resolving the contradiction between life characteristics and initial efficiency.

Inventive Principle:
Principle #3Local quality

3Reliability

If silicon oxide-based negative electrode material is used to improve life characteristics, then volume expansion is reduced, but electrical conductivity becomes low and current distribution on surface becomes non-uniform

Engineering Contradiction:
Improvebattery life characteristicsVSAvoidelectrical conductivity
Core Design Contradiction:
ReliabilityVSPower

Solution Approach 1:

The patent introduces carbon material as an intermediary substance that forms a conductive matrix surrounding silicon oxide particles. This carbon intermediary provides efficient electron transport pathways, compensating for the low electrical conductivity of silicon oxide, while the silicon oxide particles maintain their structural stability function, thus resolving the contradiction between life characteristics and electrical conductivity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite material system where carbon and silicon oxide work synergistically. The carbon phase provides electrical conductivity and current distribution uniformity, while the silicon oxide phase provides structural stability and volume expansion resistance. This composite approach resolves the contradiction between life characteristics and power by combining materials with complementary properties.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves improved initial efficiency, capacity, and life characteristics by optimizing the elemental content and doping process, leading to enhanced performance and usability of lithium secondary batteries.

Implementation Method 1

a negative electrode active material including: a silicon oxide; lithium; and sodium or potassium

Methodology Applied
Scientific EffectIon insertion/extraction: Absorption (physical)

Implementation Method 2

a negative electrode for a lithium secondary battery includes a negative electrode active material including: a silicon oxide; lithium; and sodium or potassium

Methodology Applied
Scientific EffectDoping: Dopants

Data Source

PatentUS11870065B1Negative electrode for lithium secondary battery and method of manufacturing the same
Publication Date: 2024.01.09 SK ON CO LTD

AI summary

Provided are a negative electrode for a lithium secondary battery and a method of manufacturing the same. The negative electrode for a lithium secondary battery according to an embodiment of the present invention includes a negative electrode active material including: a silicon oxide, lithium, and sodium or potassium, wherein in ICP analysis of a negative electrode active material layer including the negative electrode active material, contents of elements in the negative electrode active material layer satisfy the following Relations (1) and (2):300≤106*A/(B2+C2)≤12.0*106  (1)800≤A≤140,000  (2)wherein A is a Li content in ppm, B is a Na content in ppm, and C is a K content in ppm, based on the total weight of the ICP-analyzed negative electrode active material layer.