Silicon Oxide Batch Deposition with Controlled Oxidation Pressure

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Solution Overview

Problem

Forming silicon oxide films with high productivity and good uniformity is challenging due to the large number of Si—H and Si—CH3 bonds on multiple wafers, requiring excessive oxidizing gas and prolonged oxidation time in batch-type deposition processes.

Innovation Solution

A deposition method using a vertical heat processing apparatus that supplies a silicon material gas containing an organoamino-functionalized oligosiloxane compound and an oxidizing gas at a pressure of 1 Torr to 10 Torr, optimizing the oxidation pressure to enhance film uniformity and productivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If batch-type deposition process is used to form silicon oxide films on multiple wafers, then productivity is improved, but oxidation time becomes excessively long due to large number of Si-H and Si-CH3 bonds

Engineering Contradiction:
ImproveproductivityVSAvoidoxidation time
Core Design Contradiction:
ProductivityVSDuration of action of moving object

Solution Approach 1:

The patent changes the oxidation pressure parameter to a specific range (1-10 Torr) to optimize the oxidation process. This parameter modification enables faster oxidation kinetics while maintaining film quality, thereby reducing oxidation time and improving productivity without sacrificing film uniformity

Inventive Principle:
Principle #35Parameter changes

2Productivity

If batch-type deposition process is used to form silicon oxide films on multiple wafers, then productivity is improved, but uniformity of film thickness deteriorates

Engineering Contradiction:
ImproveproductivityVSAvoiduniformity of film thickness
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent optimizes oxidation pressure to a specific range (1-10 Torr) to achieve uniform film thickness across multiple wafers. This parameter control ensures consistent oxidation rates throughout the batch process, maintaining manufacturing precision while enabling high productivity through batch processing

Inventive Principle:
Principle #35Parameter changes

3Reliability

If excessive oxidizing gas is supplied to oxidize Si-H and Si-CH3 bonds on multiple wafers, then oxidation is improved, but process time and gas consumption increase

Engineering Contradiction:
Improveoxidation completenessVSAvoidprocess time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent modifies the oxidation pressure parameter to 1-10 Torr, which optimizes the balance between oxidation completeness and process efficiency. This pressure range enables sufficient oxidizing gas penetration and reaction while preventing excessive gas consumption and unnecessary time extension

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves good within-wafer and wafer-to-wafer uniformity of silicon oxide films with high productivity by adjusting the oxidation pressure, reducing the time required for oxidation and gas purging, while maintaining film quality.

Implementation Method 1

supplying a silicon material gas containing an organoamino-functionalized oligosiloxane compound into the processing container

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 2

supplying an oxidizing gas into the processing container adjusted to a pressure of 1 Torr to 10 Torr

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS11881396B2Deposition method
Publication Date: 2024.01.23 TOKYO ELECTRON LTD
  • US11881396B2 patent drawing
  • US11881396B2 patent drawing
  • US11881396B2 patent drawing

AI summary

A deposition method of forming silicon oxide films collectively on a plurality of substrates in a processing container performs a plurality of execution cycles each of which includes: supplying a silicon material gas containing an organoamino-functionalized oligosiloxane compound into the processing container; and supplying an oxidizing gas into the processing container adjusted to a pressure of 1 Torr to 10 Torr (133 Pa to 1333 Pa).