Silicon-Containing Patterning Stack for Tight CD Uniformity

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Solution Overview

Problem

As semiconductor fabrication processes require smaller process windows, the decreasing pitch between elements and shrinking feature dimensions pose challenges in achieving high-quality pattern density and critical dimension uniformity using traditional optical masks and photolithography equipment.

Innovation Solution

The method involves a multi-layer patterning stack comprising a carbon-containing layer, a silicon-containing layer, and a photosensitive layer, which are deposited and patterned using advanced lithography techniques such as EUV lithography. This approach improves patterning metrics like line width roughness (LWR) and local critical dimension uniformity (LCDU) by utilizing materials with high density, hardness, and etch selectivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional optical masks and photolithography equipment are used, then manufacturing simplicity is maintained, but manufacturing precision deteriorates due to inability to achieve desired pitch and critical dimension uniformity

Engineering Contradiction:
Improvecritical dimension uniformityVSAvoidpatterning process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent divides the patterning process into multiple sequential steps including mandrel formation, spacer deposition, and iterative patterning cycles. Each step creates a portion of the final pattern, allowing complex high-precision patterns to be built from simpler intermediate structures that are within the capabilities of existing lithography equipment.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent transitions from two-dimensional planar patterning to three-dimensional vertical structures by forming spacers on the sidewalls of mandrels. This vertical dimension enables pitch multiplication and achieves critical dimensions smaller than the lithography resolution limit through self-aligned processes.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Productivity

If pitch between elements is decreased to increase functional density, then productivity is improved, but manufacturing precision deteriorates due to difficulty in achieving desired spacing

Engineering Contradiction:
Improvefunctional densityVSAvoidpitch control
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The spacer formation process is self-aligned, where the spacer width is determined by the deposition thickness rather than lithographic patterning. This self-defined dimensioning automatically ensures uniform pitch spacing without requiring precise alignment, enabling high functional density with controlled spacing.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent controls pitch by adjusting deposition parameters such as spacer material thickness and composition rather than relying on lithographic resolution. By changing the deposition thickness parameter, the pitch between elements is precisely controlled independent of optical limitations.

Inventive Principle:
Principle #35Parameter changes

3Area of moving object

If feature dimensions are shrunk to increase integration, then area is reduced, but manufacturing precision deteriorates due to challenges in maintaining pattern quality at smaller scales

Engineering Contradiction:
Improvefeature sizeVSAvoidpattern quality
Core Design Contradiction:
Area of moving objectVSManufacturing precision

Solution Approach 1:

The patent performs preliminary planarization and surface preparation steps before depositing spacer materials. This preliminary action ensures uniform deposition thickness across the substrate, which directly determines spacer width and thus final feature dimensions. The preliminary preparation maintains pattern quality even as feature sizes shrink.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses composite spacer structures with different materials having complementary properties. For example, a first spacer material provides structural support while a second material provides etch selectivity or adhesion properties. This composite approach maintains pattern integrity and quality at reduced feature dimensions by optimizing each material's contribution to overall performance.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The described method enhances pattern quality by reducing line edge roughness and improving local critical dimension uniformity, allowing for more precise and dense feature formation in semiconductor devices, thereby addressing the challenges of smaller process windows and shrinking dimensions.

Implementation Method 1

a silicon-containing layer is formed over the organic bottom layer using a deposition process providing precursors delivered toward a surface of the organic bottom layer and chemically modifying the precursors to obtain the silicon-containing layer on the surface

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 2

A portion of the resist layer is exposed to a radiation to provide a patterned resist layer

Methodology Applied
Scientific EffectPhotolithography: Photography

Implementation Method 3

A portion of the silicon-containing layer uncovered by the patterned resist layer is etched to form a patterned silicon-containing layer

Methodology Applied
Scientific EffectEtching: Ablation

Data Source

PatentUS12205824B2Patterning material including silicon-containing layer and method for semiconductor device fabrication
Publication Date: 2025.01.21 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US12205824B2 patent drawing
  • US12205824B2 patent drawing
  • US12205824B2 patent drawing

AI summary

In one exemplary aspect, the present disclosure is directed to a method for lithography patterning. The method includes providing a substrate and forming a target layer over the substrate. A patterning layer is formed by depositing a first layer having an organic composition; depositing a second layer including over 50 atomic percent of silicon; and depositing a photosensitive layer on the second layer. In some implementations, the second layer is deposited by ALD, CVD, or PVD processes.