Silicon-Silicon Oxide Negative Electrode with Density Gradient

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Solution Overview

Problem

Conventional negative electrode active materials for lithium ion secondary batteries, such as those using silicon and silicon oxide, face challenges in maintaining high discharge capacity at high rates due to low electric conductivity and stress issues, which are not adequately addressed by existing techniques.

Innovation Solution

A negative electrode active material with a surface layer having lower density than the core, containing carbon and fluorine, with specific concentration ratios, enhances electric and ion conductivity, promoting higher discharge capacity at high rates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If a mixture of silicon and silicon oxide is used as the negative electrode active material, then the cycle characteristics are improved due to stress relief from silicon expansion and contraction, but the electric conductivity is low, causing remarkable deterioration in discharge capacity at high rates

Engineering Contradiction:
Improvecycle characteristicsVSAvoiddischarge capacity at high rate
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent applies local quality by creating a density gradient within the primary particle structure, where the surface layer part has lower density than the core part. This local structural differentiation allows the surface to facilitate ion transport and electron conductivity while the core maintains structural stability and stress resistance during cycling, thereby simultaneously improving both cycle characteristics and high-rate discharge capacity.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent employs composite materials by combining silicon and silicon oxide in a specific structural arrangement where silicon provides high capacity and silicon oxide provides structural stability. The composite structure is further enhanced by creating a density gradient between the core and surface layers, optimizing both mechanical stability for cycling and electrical properties for high-rate discharge.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the surface of the negative electrode active material is covered with carbon to increase electric conductivity, then the discharge capacity at high rate is improved, but the negative electrode active material itself is not substantially improved and remains insufficient

Engineering Contradiction:
Improvedischarge capacity at high rateVSAvoidstructure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by modifying the density parameter within the primary particle structure, creating a gradient from the core to the surface. This fundamental structural parameter change inherently improves electric conductivity and ion transport without requiring additional carbon coating layers, thereby achieving high-rate discharge capacity while maintaining structural simplicity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent extracts the carbon coating step from the overall structure by achieving the necessary conductivity enhancement through the density gradient structure itself. This eliminates the need for separate carbon surface coverage, simplifying the device structure while maintaining the desired electrical properties for high-rate discharge.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The described negative electrode active material structure significantly increases discharge capacity at high rates, making it suitable for use in lithium ion secondary batteries, particularly for hybrid and electric vehicles.

Implementation Method 1

a surface layer part of a primary particle of the negative electrode active material has lower density than a core part of the negative electrode active material

Methodology Applied
Scientific EffectDensity gradient effect:

Implementation Method 2

The surface layer part preferably contains carbon additionally... the surface layer part preferably contains fluorine additionally

Methodology Applied
Scientific EffectConduction (electrical): Conduction (electrical)

Data Source

PatentUS10658657B2Negative electrode active material, and negative electrode and lithium ion secondary battery using the negative electrode active material
Publication Date: 2020.05.19 TDK CORP
  • US10658657B2 patent drawing
  • US10658657B2 patent drawing

AI summary

A negative electrode active material with sufficiently high discharge capacity at a high rate, and a negative electrode and a lithium ion secondary battery using the negative electrode active material. A negative electrode active material according to the invention includes a negative electrode active material particle containing silicon and silicon oxide, wherein a surface layer part of the negative electrode active material particle is a layer with lower density than a core part of the negative electrode active material particle. With such a structure of the negative electrode active material, the sufficiently high discharge capacity at a high rate can be obtained.