Silicon Substrate Gradient Doping for Nitride Semiconductor Warpage

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Solution Overview

Problem

The existing methods for improving warpage of silicon substrates with nitride compound semiconductor layers either degrade crystallinity or incur high material costs, as increasing boron concentration enhances substrate strength but degrades crystallinity, and controlling oxygen concentration provides insufficient warpage improvement.

Innovation Solution

A silicon-based substrate with a first portion on the surface and a second portion on the inner side, where the first portion has an impurity concentration of 1×10^14 to 1×10^19 atoms/cm^3 and the second portion has a higher concentration, up to 1×10^20 atoms/cm^3, to maintain crystallinity and reduce warpage, with the first portion being 1 μm to 10 μm thick and thinner than the second portion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If boron concentration in the silicon substrate is increased to enhance substrate strength and reduce warpage, then substrate strength is improved, but crystallinity of the nitride compound semiconductor layer is degraded

Engineering Contradiction:
Improvesubstrate strengthVSAvoidcrystallinity of nitride compound semiconductor layer
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent applies local quality by creating a substrate with non-uniform impurity distribution, specifically a gradient structure where the impurity concentration varies through the thickness of the substrate. The first region (near the nitride layer) has lower impurity concentration (1×10^16 to 1×10^18 atoms/cm³) to ensure good crystallinity, while the second region (deeper in the substrate) has higher impurity concentration (1×10^19 to 1×10^20 atoms/cm³) to provide mechanical strength and reduce warpage. This spatial differentiation of impurity concentration allows simultaneous optimization of both crystallinity and substrate strength.

Inventive Principle:
Principle #3Local quality

2Strength

If the thickness of the silicon substrate is increased to reduce warpage, then substrate strength is improved, but fabrication difficulty increases due to device and jig limitations

Engineering Contradiction:
Improvesubstrate strengthVSAvoidfabrication difficulty
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent applies parameter changes by modifying the impurity concentration parameter within the substrate to achieve the desired mechanical properties. Instead of increasing substrate thickness (which would cause fabrication difficulties), the invention changes the chemical composition parameter (impurity concentration) to enhance substrate strength and reduce warpage. The specific impurity concentration range (1×10^19 to 1×10^20 atoms/cm³ in the second region) provides sufficient mechanical support while maintaining standard substrate thickness and avoiding fabrication challenges.

Inventive Principle:
Principle #35Parameter changes

3Shape

If oxygen concentration in the silicon substrate is controlled to reduce warpage, then warpage is reduced, but material cost increases and improvement is insufficient

Engineering Contradiction:
Improvewarpage of substrateVSAvoidmaterial cost
Core Design Contradiction:
ShapeVSQuantity of substance

Solution Approach 1:

The patent applies local quality by creating a gradient impurity distribution where different regions of the substrate have different impurity concentrations tailored to their specific functions. The first region near the nitride semiconductor layer has lower impurity concentration to ensure excellent crystallinity and interface quality, while the second region deeper in the substrate has higher impurity concentration to provide mechanical strength and control warpage. This localized optimization of impurity concentration achieves superior warpage control and crystallinity simultaneously, avoiding the high costs and insufficient results of uniform oxygen concentration control methods.

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS9966259B2Silicon-based substrate, semiconductor device, and method for manufacturing semiconductor device
Publication Date: 2018.05.08 SANKEN ELECTRIC CO LTD
  • US9966259B2 patent drawing
  • US9966259B2 patent drawing
  • US9966259B2 patent drawing

AI summary

A silicon-based substrate on which a nitride compound semiconductor layer is formed on a front surface thereof, including a first portion provided on the front surface side which has a first impurity concentration and a second portion provided on an inner side of the first portion which has a second impurity concentration higher than the first impurity concentration, wherein the first impurity concentration being 1×1014 atoms/cm3 or more and less than 1×1019 atoms/cm3. Consequently, there is provided the silicon-based substrate in which the crystallinity of the nitride compound semiconductor layer formed on an upper side thereof can be maintained excellently while improving a warpage of the substrate.