Silicon-Tungsten Trioxide Carbon Anode for Stable Li-Ion Capacity

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Solution Overview

Problem

Existing negative electrode materials for lithium ion batteries, such as those using carbon with tungsten trioxide on graphite, have room for improvement in performance.

Innovation Solution

A composite negative electrode material comprising carbon, tungsten trioxide, and silicon, where tungsten trioxide and silicon are formed on the surface of carbon, with specific weight ratios and crystal structures, is used to enhance performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If tungsten trioxide is arranged on the surface of graphite to improve lithium ion diffusion, then battery capacity is improved, but overall battery performance still has room for improvement

Engineering Contradiction:
Improvebattery capacityVSAvoidbattery performance
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent applies composite materials by combining carbon, tungsten trioxide, and silicon into a ternary composite structure. The carbon provides a stable base with good conductivity, tungsten trioxide forms on the carbon surface to facilitate lithium ion diffusion, and silicon is incorporated to enhance capacity. This composite approach leverages the complementary strengths of each material to achieve superior battery performance that neither material could provide alone.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If silicon is added to enhance capacity, then battery capacity increases, but structural stability may deteriorate

Engineering Contradiction:
Improvebattery capacityVSAvoidstructural stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent applies local quality by creating a heterogeneous composite structure where different materials are strategically positioned. Silicon is distributed within the carbon matrix and on the surface, surrounded by the stable carbon structure and tungsten trioxide layers. This local arrangement allows silicon to contribute its high capacity while the surrounding carbon and tungsten trioxide provide structural stability and prevent silicon from undergoing harmful volume expansion during lithium ion insertion and extraction.

Inventive Principle:
Principle #3Local quality

3Reliability

If a ternary composite structure is created to improve performance, then battery performance is enhanced, but manufacturing complexity increases

Engineering Contradiction:
Improvebattery performanceVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by pre-forming the complex ternary composite structure during the electrode manufacturing process itself. The carbon, tungsten trioxide, and silicon are combined in a slurry or coating process where the components self-assemble into the desired composite structure before being formed into the final electrode. This preliminary formation of the composite structure eliminates the need for subsequent complex assembly steps, reducing manufacturing complexity while achieving the performance benefits of the ternary composite.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite material improves the performance of lithium ion batteries by enhancing capacity and charge-discharge characteristics.

Implementation Method 1

tungsten trioxide formed on a surface of the carbon; and silicon formed on the surface of the carbon

Methodology Applied
Scientific EffectSurface deposition: Deposition (physical)

Implementation Method 2

Arranging tungsten trioxide on the surface of graphite can improve diffusion of a lithium ion

Methodology Applied
Scientific EffectIon diffusion: Diffusion

Data Source

PatentUS12573612B2Negative electrode material, battery, method for producing negative electrode material, and method for producing battery
Publication Date: 2026.03.10 MITSUBISHI MATERIALS CORP
  • US12573612B2 patent drawing
  • US12573612B2 patent drawing
  • US12573612B2 patent drawing

AI summary

A negative electrode material is a negative electrode material for a battery, and the material includes carbon, tungsten trioxide formed on the surface of the carbon, and silicon formed on the surface of the carbon.