Silicon-Tungsten Trioxide Carbon Anode for Stable Li-Ion Capacity
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Solution Overview
Problem
Existing negative electrode materials for lithium ion batteries, such as those using carbon with tungsten trioxide on graphite, have room for improvement in performance.
Innovation Solution
A composite negative electrode material comprising carbon, tungsten trioxide, and silicon, where tungsten trioxide and silicon are formed on the surface of carbon, with specific weight ratios and crystal structures, is used to enhance performance.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Quantity of substance
If tungsten trioxide is arranged on the surface of graphite to improve lithium ion diffusion, then battery capacity is improved, but overall battery performance still has room for improvement
Solution Approach 1:
The patent applies composite materials by combining carbon, tungsten trioxide, and silicon into a ternary composite structure. The carbon provides a stable base with good conductivity, tungsten trioxide forms on the carbon surface to facilitate lithium ion diffusion, and silicon is incorporated to enhance capacity. This composite approach leverages the complementary strengths of each material to achieve superior battery performance that neither material could provide alone.
2Quantity of substance
If silicon is added to enhance capacity, then battery capacity increases, but structural stability may deteriorate
Solution Approach 1:
The patent applies local quality by creating a heterogeneous composite structure where different materials are strategically positioned. Silicon is distributed within the carbon matrix and on the surface, surrounded by the stable carbon structure and tungsten trioxide layers. This local arrangement allows silicon to contribute its high capacity while the surrounding carbon and tungsten trioxide provide structural stability and prevent silicon from undergoing harmful volume expansion during lithium ion insertion and extraction.
3Reliability
If a ternary composite structure is created to improve performance, then battery performance is enhanced, but manufacturing complexity increases
Solution Approach 1:
The patent applies preliminary action by pre-forming the complex ternary composite structure during the electrode manufacturing process itself. The carbon, tungsten trioxide, and silicon are combined in a slurry or coating process where the components self-assemble into the desired composite structure before being formed into the final electrode. This preliminary formation of the composite structure eliminates the need for subsequent complex assembly steps, reducing manufacturing complexity while achieving the performance benefits of the ternary composite.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The composite material improves the performance of lithium ion batteries by enhancing capacity and charge-discharge characteristics.
Implementation Method 1
tungsten trioxide formed on a surface of the carbon; and silicon formed on the surface of the carbon
Implementation Method 2
Arranging tungsten trioxide on the surface of graphite can improve diffusion of a lithium ion
Data Source
AI summary
A negative electrode material is a negative electrode material for a battery, and the material includes carbon, tungsten trioxide formed on the surface of the carbon, and silicon formed on the surface of the carbon.


