Moisture-Curable Hot Melt Silicone Adhesive for Structural Glazing

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Solution Overview

Problem

Current structural glazing systems lack a transparent bonding solution that maximizes natural lighting and aesthetics by effectively bonding glass panels to frames, while maintaining structural integrity and weatherproofing.

Innovation Solution

A structural glazing assembly using a moisture-curable hot melt silicone adhesive composition with a reactive resin, reactive polymer, moisture cure catalyst, and crosslinker, applied between a glass panel and a frame/support, optionally with a transparent spacer, to create a transparent and durable bond.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a structural silicone sealant is used to bond glass panels to frames, then structural integrity is achieved, but transparency and natural lighting are reduced

Engineering Contradiction:
Improveadhesive strengthVSAvoidnatural lighting
Core Design Contradiction:
StrengthVSIllumination intensity

Solution Approach 1:

The patent changes the chemical composition parameters of the silicone adhesive by incorporating specific ratios of reactive resins, reactive polymers, and crosslinking agents. This creates a cured adhesive with optimized optical properties (transparency) while maintaining mechanical bonding strength, resolving the contradiction between strength and transparency.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The adhesive is formulated as a composite material system containing multiple components: silicone base polymers, reactive resins for crosslinking, fillers for transparency enhancement, and catalytic agents. This composite structure enables simultaneous achievement of structural integrity and optical clarity.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the bite dimension is increased to accommodate higher wind loads, then structural reliability is improved, but the adhesive layer thickness must be increased which affects installation complexity

Engineering Contradiction:
Improvestructural reliabilityVSAvoidinstallation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies the rheological parameters of the adhesive composition by adjusting viscosity through polymer selection and crosslinking density. This enables the adhesive to maintain high bonding strength at reduced thicknesses, allowing smaller bite dimensions while preserving structural reliability and simplifying installation.

Inventive Principle:
Principle #35Parameter changes

3Illumination intensity

If a transparent adhesive is used to maximize natural lighting, then aesthetics and illumination are improved, but adhesive strength and creep resistance may be reduced

Engineering Contradiction:
Improvenatural lightingVSAvoidadhesive strength
Core Design Contradiction:
Illumination intensityVSStrength

Solution Approach 1:

The transparent adhesive is formulated as a composite containing silicone polymers for flexibility, reactive resins for strength development, and specifically selected fillers that maintain transparency while contributing to mechanical properties. This composite approach enables simultaneous achievement of optical clarity and high bonding strength with creep resistance.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides improved natural lighting, enhanced aesthetics, and increased adhesive strength with improved creep resistance, while maintaining the structural integrity and weatherproofing of the glazing system.

Implementation Method 1

a moisture-curable hot melt silicone adhesive composition comprising: (A) a reactive resin, (B) a reactive polymer, (C) a moisture cure catalyst, and (D) a crosslinker

Methodology Applied
Scientific EffectMoisture-cure catalysis: Catalysis

Implementation Method 2

a crosslinker... wherein the silicone elastomer is the cured elastomeric product of a moisture-curable hot melt silicone adhesive composition

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Data Source

PatentEP3513024B1Moisture-curable hot melt silicone adhesive compositions including an alkoxy-functional siloxane reactive resin and structural glazing
Publication Date: 2024.11.20 DOW SILICONES CORP
  • EP3513024B1 patent drawingFigure 1

AI summary

A structural glazing assembly comprising a frame and a transparent panel optionally spaced apart by a transparent spacer material said frame and said panel being adhered to each other by a layer of a transparent silicone elastomer located there between. Typically the silicone elastomer is the cured elastomeric product of a moisture-curable hot melt silicone adhesive composition.