Heat-Conductive Silicone Composition for CPU Thermal Interface Gaps

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Solution Overview

Problem

Existing thermal conductive materials and greases are inadequate for effectively dissipating the heat generated by modern integrated circuit elements such as CPUs.

Innovation Solution

A thermal conductive silicone composition comprising organopolysiloxane, silver powder, elemental gallium and/or gallium alloy, and a catalyst, with specific properties to enhance thermal conductivity and handling properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional thermal conductive materials (aluminum nitride powder, zinc oxide powder, diamond powder) are used in silicone grease, then thermal conductivity is improved to some extent, but the heat dissipation capability is still insufficient for modern high-performance integrated circuit elements

Engineering Contradiction:
Improveheat dissipation capabilityVSAvoidadequacy for modern CPU thermal management
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent employs a composite filler system combining silver powder (high thermal conductivity: 429 W/mK) with aluminum nitride powder (70-270 W/mK) and zinc oxide powder (17-37 W/mK). This multi-material composite approach creates synergistic effects where silver provides exceptional thermal conduction pathways while aluminum nitride and zinc oxide fill interstitial spaces and contribute additional conduction routes, achieving thermal conductivity of 8.0 W/mK or higher in the grease composition that exceeds any single filler material's performance in this application context.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent systematically optimizes critical parameters including silver powder particle size distribution (combining fine particles of 0.1-10 μm with coarse particles of 10-100 μm), filler content (30-80 wt% total filler), and grease consistency (viscosity 10-1000 cP). These parameter changes transform the thermal conduction mechanism by creating dense filler packing with minimized void spaces, maximizing thermal contact between filler particles and enabling the grease to achieve sufficient heat dissipation for modern CPUs.

Inventive Principle:
Principle #35Parameter changes

2Temperature

If higher filler content is used to improve thermal conductivity, then heat dissipation property is enhanced, but the grease consistency and ease of application deteriorate

Engineering Contradiction:
Improvethermal conductivityVSAvoidgrease consistency and applicability
Core Design Contradiction:
TemperatureVSEase of operation

Solution Approach 1:

The patent maintains grease consistency within the optimal range of 10-1000 cP by carefully controlling the total filler content at 30-80 wt% and selecting base grease viscosity accordingly. This parameter optimization ensures the grease remains sufficiently fluid for easy application while containing enough filler to achieve the required thermal conductivity of 8.0 W/mK or higher, resolving the contradiction between thermal performance and ease of operation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a bimodal particle size distribution strategy where fine silver powder particles (0.1-10 μm) fill the interstitial spaces between larger aluminum nitride and zinc oxide particles (10-100 μm). This local quality differentiation creates a dense, space-efficient packing structure that maximizes thermal conduction pathways while minimizing the total volume occupied by filler, thereby maintaining better grease consistency and workability at higher filler loadings.

Inventive Principle:
Principle #3Local quality

3Temperature

If finer particle size filler is used to improve thermal conductivity, then heat dissipation property is enhanced, but the viscosity and handling difficulty increase

Engineering Contradiction:
Improvethermal conductivityVSAvoidviscosity and handling property
Core Design Contradiction:
TemperatureVSEase of operation

Solution Approach 1:

The patent creates a hierarchical filler structure where fine silver powder particles (0.1-10 μm) are distributed within and between larger aluminum nitride and zinc oxide particles (10-100 μm). This local quality differentiation allows fine particles to occupy interstitial voids and create additional thermal conduction pathways without significantly increasing overall viscosity, as the larger particles provide a skeletal framework that prevents excessive fine particle aggregation and maintains grease fluidity.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The multi-component filler composite (silver + aluminum nitride + zinc oxide) with differentiated particle sizes creates a synergistic structure where each component serves multiple functions: fine silver particles provide high-conductivity pathways, larger particles provide structural framework, and the combination maintains optimal viscosity by preventing excessive fine particle content that would otherwise increase handling difficulty.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition provides superior heat dissipation, suitable for semiconductor devices, addressing the thermal management challenges of high-performance integrated circuits.

Implementation Method 1

The thermal conductivity of aluminum nitride is 70 to 270 W/mK. Diamond is known as a material having a thermal conductivity higher than that of aluminum nitride, and has a thermal conductivity of 900 to 2,000 W/mK.

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 2

an elemental gallium and/or gallium alloy (C) having a low melting point

Methodology Applied
Scientific EffectPhase change: Phase Change

Data Source

PatentEP3901998B1Heat-conductive silicone composition and semiconductor device
Publication Date: 2025.10.15 SHIN ETSU CHEMICAL CO LTD
  • EP3901998B1 patent drawingFigure 1
  • EP3901998B1 patent drawing
  • EP3901998B1 patent drawing

AI summary

Provided are a heat-conductive silicone composition having good heat dissipation characteristics, and a semiconductor device using the said composition. A heat-conductive silicone composition containing: (A) an organopolysiloxane expressed by average composition formula (1): Formula (1): R1aSiO(4-a)/2 (In the formula, R1 represents a hydrogen atom, a C1-18 saturated or unsaturated univalent hydrocarbon group, or a hydroxy group, and a satisfies the expression 1.8 ≤ a ≤ 2.2), the organopolysiloxane having kinetic viscosity at 25°C of 10-100,000 mm2/s; (B) silver powder having a tapped density of 3.0 g/cm3 or more, a specific surface area of 2.0 m2/g or less, and an aspect ratio of 1-30; (C) elemental gallium and/or a gallium alloy having a melting point of 0-70°C, the mass ratio [component (C)/{component (B) + component (C)}] being 0.001-0.1; and (D) a catalyst selected from the group consisting of platinum catalysts, organic peroxides, and condensation reaction catalysts.