Polyether-Modified Silicone Composition for Stable Polyurethane Foam Premixes

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Solution Overview

Problem

Existing polyether-modified silicone compositions face challenges in industrial production due to poor storage stability, handling issues, and compatibility with polyurethane foam components, leading to unsatisfactory foam performance and increased environmental and economic costs.

Innovation Solution

A polyether-modified silicone composition comprising specific polyether-modified silicone and a monool organic compound, such as glycol ether, with limited isopropyl alcohol content, used in a hydrosilylation reaction to enhance mixing stability and reduce volatile organic compounds, ensuring low-cost, safe, and environmentally friendly production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If polyether-modified silicone is used as surfactant in polyurethane foam formulations, then surfactant activity and foam stability are improved, but storage stability of premix solution deteriorates due to hydrogel formation

Engineering Contradiction:
Improvefoam stabilityVSAvoidstorage stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent introduces a specific organic solvent as an intermediary substance to mediate between the polyether-modified silicone and water. This solvent prevents direct interaction that would cause hydrogel formation, thereby maintaining storage stability while preserving the surfactant's foam-stabilizing function. The solvent acts as a compatibility agent that bridges the hydrophobic silicone and hydrophilic water phases.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the chemical environment by changing the solvent parameters - specifically selecting an organic solvent with appropriate polarity and solubility characteristics. This parameter change prevents the phase separation and gelation that occur in water-based systems, allowing the polyether-modified silicone to remain stable in premix solutions while retaining its surfactant activity.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If vacuum stripping is used to remove volatile organic solvents after hydrosilylation, then cell stability is improved, but production efficiency deteriorates due to slow pressure reduction

Engineering Contradiction:
Improvecell stabilityVSAvoidproduction efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent extracts and removes the volatile organic solvent component from the system after the hydrosilylation reaction. By completely removing the solvent rather than leaving it in the system, the patent eliminates the need for slow vacuum stripping during production. The solvent-free system allows for faster processing while maintaining cell stability through the chemical structure of the polyether-modified silicone itself.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent performs the solvent removal action during the reaction process itself rather than as a subsequent slow vacuum stripping step. By integrating the solvent elimination into the hydrosilylation process, the patent achieves both complete solvent removal for cell stability and efficient production timing, eliminating the bottleneck of slow pressure reduction.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If high boiling point polyol solvent is used for hydrosilylation to avoid vacuum stripping, then production efficiency is improved, but side reactions increase due to poor affinity with SiH group-containing organopolysiloxane

Engineering Contradiction:
Improveproduction efficiencyVSAvoidreaction selectivity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent uses a specifically selected organic solvent as an intermediary that provides good affinity with SiH group-containing organopolysiloxane. This intermediary solvent facilitates the hydrosilylation reaction by improving mixing and contact between reactants, thereby increasing reaction rate and selectivity while avoiding the need for vacuum stripping and maintaining production efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes the solvent parameters by selecting an organic solvent with appropriate boiling point, polarity, and chemical compatibility. This parameter optimization achieves the right balance: high enough boiling point to avoid excessive evaporation but low enough to allow efficient removal, while providing good solubility for the SiH-containing polysiloxane to prevent side reactions and maintain manufacturing precision.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP3530703B1Polyether-modified silicone composition, surfactant, foam stabilizer, polyurethane foam forming composition, and cosmetic preparation including said composition, and method for producing said composition
Publication Date: 2026.03.11 DOW TORAY CO LTD
  • EP3530703B1 patent drawing
  • EP3530703B1 patent drawing
  • EP3530703B1 patent drawing

AI summary

[Problem] To provide a polyether-modified silicone composition that can be supplied in large quantities at low cost, that is very safe and environmentally friendly, and that has excellent quality in terms of mixing stability, handling and workability, and storage stability in compositions containing a dispersion medium, and that can be used in applications such as surfactants and foam stabilizers, to provide applications for this polyether-modified silicone composition, and to provide a manufacturing method for this polyether-modified silicone composition. [Solution] Provided is a polyether-modified silicone composition comprising (A) a polyether-modified silicone, and (B) a monool organic compound selected from (B1) a glycol ether compound having a hydrogen atom substituted by an alkyl group having from 2 to 8 carbon atoms at one end, a secondary alcoholic hydroxy group at the other end, from 2 to 3 repeating oxyalkylene units having from 2 to 4 carbon atoms, and (B2) a tripropylene glycol monomethyl ether, wherein isopropyl alcohol does not exceed 1 mass% of the entire composition; applications for this composition; and a manufacturing method for this composition.