Silicone Grease Composition for Thermal Interface Materials

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Solution Overview

Problem

Conventional heat dissipating greases fail to effectively manage the increased heat release from advanced electronic components like CPUs due to limitations in filler loading and particle size, which affect thermal conductivity and application efficiency.

Innovation Solution

A silicone grease composition with an organopolysiloxane and a heat conductive filler, such as copper powder, is developed, where coarse particles are removed to ensure a high fraction of particles pass through 500-mesh and 325-mesh sieves, allowing for a reduced coating thickness and improved heat transfer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If heavier loading of heat conductive filler is used to enhance heat dissipation, then thermal conductivity is improved, but viscosity increases and ease of application deteriorates

Engineering Contradiction:
Improveheat dissipationVSAvoidease of application
Core Design Contradiction:
TemperatureVSEase of operation

Solution Approach 1:

The patent changes the particle size parameter of the heat conductive filler to a specific range (0.1 to 15.0 μm average particle size) and controls the distribution of particle sizes to achieve optimal packing density. This parameter optimization allows high filler loading (60-98% by weight) while maintaining acceptable viscosity and ease of application, resolving the contradiction between heat dissipation performance and applicability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite approach by combining heat conductive filler particles of different size ranges within the specified distribution. This composite particle size distribution enables better packing efficiency and thermal conductivity while controlling the viscosity characteristics, allowing the grease to maintain both high heat dissipation performance and ease of application.

Inventive Principle:
Principle #40Composite materials

2Temperature

If smaller average particle size of heat conductive filler is used to reduce coating thickness, then thermal resistance is reduced, but coarse particles remain and prevent desired coating thickness

Engineering Contradiction:
Improvethermal resistanceVSAvoidcoating thickness control
Core Design Contradiction:
TemperatureVSManufacturing precision

Solution Approach 1:

The patent optimizes the particle size parameter by specifying a narrow average particle size range (0.1 to 15.0 μm) and controlling the coarse particle content to not more than 50 ppm. This precise parameter control ensures that the filler particles are fine enough to achieve thin coatings with low thermal resistance, while the strict limitation on coarse particles prevents coating defects and enables precise thickness control.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent extracts and removes coarse particles from the heat conductive filler through careful selection and processing, limiting coarse particles to not more than 50 ppm. This extraction of problematic coarse particles allows the grease to be coated to the desired thin thickness without interruption or defects, resolving the contradiction between reducing thermal resistance and achieving uniform thin coating.

Inventive Principle:
Principle #2Taking out (Extraction)

3Ease of operation

If conventional heat dissipating grease is used, then ease of application is maintained, but heat dissipation performance is insufficient for advanced electronic components

Engineering Contradiction:
Improveease of applicationVSAvoidheat dissipation performance
Core Design Contradiction:
Ease of operationVSTemperature

Solution Approach 1:

The patent optimizes multiple parameters simultaneously: filler particle size (0.1 to 15.0 μm average), filler loading (60-98% by weight), and coarse particle content (not more than 50 ppm). These parameter changes collectively enhance thermal conductivity and heat dissipation performance while maintaining ease of application, allowing the grease to meet the demands of advanced high heat-generating electronic components.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite material system with a specific organopolysiloxane base and a carefully distributed heat conductive filler composite. The composite structure with controlled particle size distribution enables both high thermal conductivity for superior heat dissipation and appropriate rheological properties for ease of application, overcoming the limitations of conventional single-component heat dissipating greases.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves excellent heat dissipation and transfer with a drastically improved thermal conductivity and ease of application, suitable for high heat-generating electronic components.

Implementation Method 1

a heat conductive filler selected from among metal powders, metal oxide powders and ceramic powders having a thermal conductivity of at least 10 W/m°C

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentUS7510998B2Silicon grease compositions
Publication Date: 2009.03.31 SHIN ETSU CHEMICAL CO LTD
  • US7510998B2 patent drawing
  • US7510998B2 patent drawing
  • US7510998B2 patent drawing

AI summary

A silicone grease composition is provided comprising (A) 2-40% by weight of an organopolysiloxane having a kinematic viscosity of 50-500,000 mm2/s at 25° C., and (B) 60-98% by weight of at least one heat conductive filler selected from among metal powders, metal oxide powders and ceramic powders having a thermal conductivity of at least 10 W/m° C. and an average particle size of 0.1-15.0 μm. Coarse particles are removed such that a 500-mesh oversize fraction is not more than 50 ppm and a 325-mesh oversize fraction is substantially zero.