Two-Component Developer with Silicone Oil Modified Inorganic Particles

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Solution Overview

Problem

The existing two-component developer systems for electrostatic latent image development face challenges in preventing lead portion whitening and development leakage, especially during initial stages and prolonged use, due to scavenging phenomena caused by differences in moving speeds between the developing sleeve and photoreceptor.

Innovation Solution

A two-component developer is designed with toner particles and carrier particles, where inorganic particles are surface-modified with silicone oil, maintaining a specific carbon content and free carbon ratio, and a resin covering layer containing an alicyclic methacrylic acid ester monomer is used to control the carrier particle resistance, preventing scavenging and leakage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If the resistance of carrier particles is excessively lowered to suppress scavenging phenomenon, then lead portion whitening is prevented, but development leakage occurs and image defects arise

Engineering Contradiction:
Improvelead portion whiteningVSAvoiddevelopment leakage
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent applies parameter changes by precisely controlling the resistance of carrier particles within a specific range (1.0×10^9 to 5.0×10^10 Ω·cm) rather than excessively lowering it. This optimized resistance parameter suppresses scavenging and lead portion whitening while preventing development leakage and image defects, resolving the contradiction between suppressing whitening and preventing leakage.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining carrier particles with specific resistance properties and inorganic particles surface-modified with silicone oil. This composite structure allows the developer to simultaneously achieve low enough resistance to prevent scavenging while maintaining high enough resistance to prevent development leakage, resolving the technical contradiction.

Inventive Principle:
Principle #40Composite materials

2Productivity

If the moving speed of developing sleeve is set higher than photoreceptor to improve development speed, then productivity increases, but scavenging phenomenon occurs

Engineering Contradiction:
Improvedevelopment speedVSAvoidscavenging phenomenon
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the electrical parameter (resistance) of the carrier particles to optimize the development process. By controlling carrier particle resistance within a specific range, the system can maintain higher developing sleeve speeds for improved productivity while preventing scavenging through optimized charge characteristics.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces inorganic particles surface-modified with silicone oil as an intermediary substance that mediates between the toner and carrier particles. This intermediary modifies the surface properties and charge characteristics, allowing the developing sleeve to rotate at higher speeds without causing scavenging phenomena.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration effectively suppresses lead portion whitening at the initial stage and prevents development leakage even during extended use by optimizing the transfer of silicone oil and maintaining suitable resistance levels, ensuring stable image development.

Implementation Method 1

inorganic particles contained in an external additive of the toner particles are surface-modified with silicone oil

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

an electrostatic latent image formed on an image carrier (it is also called as a photoreceptor) is developed with a toner

Methodology Applied
Scientific EffectElectrostatic: Electrostatics

Data Source

PatentUS10437166B2Two-component developer for developing electrostatic latent image
Publication Date: 2019.10.08 KONICA MINOLTA INC
  • US10437166B2 patent drawing
  • US10437166B2 patent drawing

AI summary

Provided is a two-component developer for developing an electrostatic latent image incorporating: toner particles each containing a toner mother particle having an external additive on a surface of the toner mother particle; and carrier particles each having a core material particle and a covering layer containing a resin on a surface of the core material particle, wherein the external additive contains inorganic particles; the inorganic particles are subjected to surface modification with silicone oil; a carbon content remained on a surface of the inorganic particle after the surface modification is within 3.0 to 10.0 mass %; a free carbon ratio on the surface of the inorganic particle is 70.0% or more; the carrier particles have a resistance in the range of 1.0×109 to 5.0×1010 Ω·cm; and the resin in the covering layer contains a resin formed from a monomer containing an alicyclic methacrylic acid ester monomer.